Chitosan modified multi-walled carbon nanotubes and arginine aerogel for enhanced carbon capture.

Global warming is emerging as a significant issue because of increasing CO levels in the atmosphere due to urbanization, industrialization, and fossil-fuel usage. Therefore, reducing atmospheric CO levels using new materials with high carbon capture capacity and efficient CO capture technologies is essential. Herein, we propose a hybrid chitosan (CS) aerogel containing multi-walled carbon nanotubes (MWCNTs) and an arginine (Arg) aerogel (CSCNTArg aerogel) for efficient carbon capture. This aerogel was successfully synthesized using a cross-linker reagent via step-freeze drying method. Fourier-transform infrared spectroscopy and X-ray diffraction analyses confirmed the successful grafting of CS, MWCNTs, and Arg onto the CSCNTArg aerogel. The thermogravimetric analysis (TGA) confirmed good thermal stability up to 500 °C of the as-developed aerogel. Field-emission scanning electron microscopy showed that the surface morphology of the CSCNTArg aerogel differed from that of CS, Arg, and MWCNTs with pores on their surfaces. N and CO adsorption-desorption studies on the CSCNTArg aerogel were performed using the Brunauer-Emmett-Teller method and TGA, respectively. The CSCNTArg aerogel showed a high adsorption capacity of approximately 5.00 mmol g at 35 °C. Therefore, this new material may be useful for facilitating high-efficiency CO adsorption to reduce atmospheric carbon footprint.