Zhou Jixi, Lan Di, Zhang Feng, Cheng Yuhang, Jia Zirui, Wu Guanglei, Yin Pengfei
College of Science, Sichuan Agricultural University, Ya'an, 625014, P. R. China.
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao, 442002, P. R. China.
Small. 2023 Dec;19(52):e2304932. doi: 10.1002/smll.202304932. Epub 2023 Aug 27.
Reasonable composition design and controllable structure are effective strategies for harmonic electromagnetic wave (EMW) adsorption of multi-component composites. On this basis, the hybrid MoS /CoS /VN multilayer structure with the triple heterogeneous interface is prepared by simple stirring hydrothermal, which can satisfy the synergistic interaction between different components and obtain excellent EMW absorption performance. Due to the presence of multiple heterogeneous interfaces, MoS /CoS /VN composites will produce strong interfacial polarization, while the defects in the sample will become the center of polarization, resulting in dipole polarization. Due to the excellent structural design of MoS /CoS /VN composite material, MoS /CoS /VN composite material not only has good conductive loss and polarization loss, but also can maintain excellent stability in simulated seawater, and enhance corrosion resistance. The MoS /CoS /VN composite with dual functions of corrosion resistant and microwave absorption achieves a minimum reflection loss (RL) of -50.48 dB and an effective absorption bandwidth of up to 5.76 GHz, covering both the X-band and Ku-band. Finally, this study provides a strong reference for the development of EMW absorption materials based on transition metal nitrides.
合理的成分设计和可控的结构是多组分复合材料实现谐波电磁波(EMW)吸收的有效策略。在此基础上,通过简单的搅拌水热法制备了具有三重异质界面的MoS₂/CoS₂/VN多层结构,该结构能够满足不同组分之间的协同相互作用,并获得优异的EMW吸收性能。由于存在多个异质界面,MoS₂/CoS₂/VN复合材料会产生强烈的界面极化,而样品中的缺陷将成为极化中心,从而导致偶极极化。由于MoS₂/CoS₂/VN复合材料出色的结构设计,该复合材料不仅具有良好的传导损耗和极化损耗,而且在模拟海水中能保持优异的稳定性,并增强耐腐蚀性。具有耐腐蚀和微波吸收双重功能的MoS₂/CoS₂/VN复合材料实现了-50.48 dB的最小反射损耗(RL)和高达5.76 GHz的有效吸收带宽,覆盖了X波段和Ku波段。最后,该研究为基于过渡金属氮化物的EMW吸收材料的开发提供了有力参考。