Zainudeen N M, Mohammed L, Nyamful A, Adotey D, Osae S K
Department of Nuclear Sciences and Applications, School of Nuclear and Allied Sciences, University of Ghana, P.O. Box LG 80, Legon, Accra, Ghana.
Institute of Scientific & Technological Information, Council for Scientific and Industrial Research, P. O. Box CT 2211, Cantonments, Accra, Ghana.
Heliyon. 2023 Aug 12;9(8):e19070. doi: 10.1016/j.heliyon.2023.e19070. eCollection 2023 Aug.
Bauxite, which is the main raw material that aluminium is extracted from was discovered in Africa in the early 1900s. Currently, the production and export capacities of the African Bauxite ore are about a third of the World's total capacity. However, the processes leading to the final finished product of; surface mining of the ore, refining ore into alumina and finally extracting the pure aluminium metal in high energy consuming smelters that employ the Hall-Héroult electrolysis process; seldom take place inside Africa. The main goal of this work is to analyse the mineralogical and geochemical characteristics of bauxite deposits from some prominent bauxite producing and exporting countries of Africa in order to fashion out if a trend exist for the type of source rocks. Judging from the data obtained, gibbsite is found to be the main aluminium oxide in all the bauxite deposits with slight occurrence of boehmite in 3 out of the 13 deposits, while goethite is the main oxyhydroxide iron mineral. The compiled results of the various investigations highlighted the fact that the deposits are of diverse qualities with respect to world standard of major element content of bauxite; with average percentage concentration in the ranges as: AlO (43.73-61.25), FeO (1.55-34.25), SiO (0.42-10.84); except two of the deposits with alumina content less than 40%. With evaluated silica moduli less than 8 for only two (2) of the deposits (4.76 and 6.94), the rest have higher moduli that ranges between (14.49 and 75.45). The higher percentage of iron oxide content (>20) in six (6) out of the 13 ore deposits, allowed the deposits to be grouped into three (3) categories of grades; high alumina ore, ferruginous ore, siliceous ore and combination of each. Source rock of the deposits were determined through geochemical and petrographic considerations of laterisation products of the rocks through evaluation of the weathering indices of; Chemical Index of Alteration which was in the range (97.16-99.98) while the Ruxton ratio ranged between (0.0133-0.2100); signifying the parent rock underwent intensive weathering process. This is indicative of the source rocks of the Bauxite deposits being either (i) anorthositic, (ii) argillite and dolerite, (iii) granulite and feldspathic gneiss, and/or, (iv) mafic-basaltic andesite igneous. Awareness of new and yet-to-commence emerging bauxite producing African countries was created, by highlighting the economic impact those respective countries will experience when that mining sector is developed for the aluminum industry at home and world at large.
铝土矿是提取铝的主要原材料,于20世纪初在非洲被发现。目前,非洲铝土矿的生产和出口能力约占世界总能力的三分之一。然而,从矿石的露天开采、将矿石提炼成氧化铝,到最终在采用霍尔-埃鲁电解法的高能耗冶炼厂中提取纯铝金属,这些最终成品的生产过程很少在非洲境内进行。这项工作的主要目标是分析非洲一些主要铝土矿生产和出口国的铝土矿矿床的矿物学和地球化学特征,以便确定源岩类型是否存在某种趋势。从获得的数据来看,三水铝石是所有铝土矿矿床中的主要氧化铝,在13个矿床中有3个矿床少量出现了勃姆石,而针铁矿是主要的羟基氧化铁矿物。各项调查的汇总结果突出表明,就铝土矿主要元素含量的世界标准而言,这些矿床质量各异;平均百分比浓度范围如下:AlO(43.73 - 61.25)、FeO(1.55 - 34.25)、SiO(0.42 - 10.84);只有两个矿床的氧化铝含量低于40%。在评估的矿床中,只有两个矿床(4.76和6.94)的硅模量小于8,其余矿床的硅模量较高,范围在(14.49和75.45)之间。13个矿床中有6个矿床的氧化铁含量百分比更高(>20),这使得这些矿床可分为三类品位;高铝矿、铁铁矿、硅质矿以及它们各自的组合。通过评估风化指数,即化学蚀变指数(范围为97.16 - 99.98)和鲁克斯顿比率(范围为0.0133 - 0.2100),从地球化学和岩石学角度考虑岩石的红土化产物,从而确定了矿床的源岩;这表明母岩经历了强烈的风化过程。这表明铝土矿矿床的源岩要么是(i)斜长岩,(ii)泥质岩和辉绿岩,(iii)麻粒岩和长石片麻岩,和/或,(iv)镁铁质 - 玄武安山岩火成岩。通过强调这些非洲新兴铝土矿生产国在为国内和全球铝工业开发采矿业时将经历的经济影响,提高了对这些国家的认识。