Faller Jack, Parr Jonathan
Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520-8107, USA.
Acta Crystallogr C Struct Chem. 2023 Sep 1;79(Pt 9):381-385. doi: 10.1107/S2053229623007325. Epub 2023 Aug 26.
The structure of a platinum(II) complex containing (R)-(dimethylamino)ethylnapthyl and bis(diphenylphosphanyl)methane monosulfide ligands, namely, {(R)-1-[1-(dimethylamino)ethyl]napthyl-κN,C}[(diphenylphosphanylmethyl)diphenylphosphine sulfide-κP,S]platinum(II) hexafluoridoantimonate dichloromethane monosolvate, [Pt(CHN)(CHPS)][SbF]·CHCl, was determined. The structural features are compared with analogous platinum bis(diphenylphosphanyl)methane monoxide [dppm(O)] and bis(diphenylphosphanyl)methane monoselenide [dppm(Se)] complexes in relation to their potential hemilability and stereochemical nonrigidity.
测定了一种含有（R）-（二甲基氨基）乙基萘基和双（二苯基膦基）甲烷单硫化物配体的铂（II）配合物的结构，即六氟锑酸二氯甲烷单溶剂合物{（R）-1-[1-（二甲基氨基）乙基]萘基-κN，C}[（二苯基膦基甲基）二苯基膦硫化物-κP，S]铂（II），[Pt（CHN）（CHPS）][SbF]·CHCl。将其结构特征与类似的铂双（二苯基膦基）甲烷单氧化物[dppm（O）]和双（二苯基膦基）甲烷单硒化物[dppm（Se）]配合物在潜在的半活性和立体化学非刚性方面进行了比较。
