Lai Beibei, Liu Siyuan, Cahir John, Sun Yueting, Yin Haixia, Youngs Tristan, Tan Jin-Chong, Fonrouge Sergio F, Pópolo Mario G Del, Borioni José L, Crawford Deborah E, Alexander Francesca M, Li Chunchun, Bell Steven E J, Murrer Barry, James Stuart L
School of Chemistry and Chemical Engineering, Queen's University Belfast, Belfast, Northern Ireland, BT9 5AG, UK.
School of Engineering, University of Birmingham, Birmingham, B15 2TT, UK.
Adv Mater. 2023 Nov;35(44):e2306521. doi: 10.1002/adma.202306521. Epub 2023 Sep 20.
Compressibility is a fundamental property of all materials. For fluids, that is, gases and liquids, compressibility forms the basis of technologies such as pneumatics and hydraulics and determines basic phenomena such as the propagation of sound and shock waves. In contrast to gases, liquids are almost incompressible. If the compressibility of liquids could be increased and controlled, new applications in hydraulics and shock absorption could result. Here, it is shown that dispersing hydrophobic porous particles into water gives aqueous suspensions with much greater compressibilities than any normal liquids such as water (specifically, up to 20 times greater over certain pressure ranges). The increased compressibility results from water molecules being forced into the hydrophobic pores of the particles under applied pressure. The degree of compression can be controlled by varying the amount of porous particles added. Also, the pressure range of compression can be reduced by adding methanol or increased by adding salt. In all cases, the liquids expand back to their original volume when the applied pressure is released. The approach shown here is simple and economical and could potentially be scaled up to give large amounts of highly compressible liquids.
可压缩性是所有材料的基本属性。对于流体,即气体和液体,可压缩性构成了诸如气动和液压等技术的基础,并决定了诸如声音和冲击波传播等基本现象。与气体不同,液体几乎不可压缩。如果能够提高并控制液体的可压缩性,那么在液压和减震方面可能会产生新的应用。在此表明,将疏水性多孔颗粒分散到水中会得到水悬浮液,其可压缩性比任何普通液体(如水)都大得多(具体而言,在某些压力范围内高达20倍)。可压缩性的增加是由于在施加压力下,水分子被迫进入颗粒的疏水孔中。压缩程度可以通过改变添加的多孔颗粒的量来控制。此外,添加甲醇可以减小压缩的压力范围,添加盐则可以增大压力范围。在所有情况下,当释放施加的压力时,液体都会膨胀回到其原始体积。此处所示的方法简单且经济,并且有可能扩大规模以获得大量高可压缩性液体。