通过镍催化的光还原交叉偶联合成2-吲哚基-糖苷新岩藻素A和C及其类似物。
Synthesis of 2-Indolyl -Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling.
作者信息
Xia Yan, Wang Yingjie, Zhang Zhaolun, Gulzar Tayyab, Lin Yuqi, Wang Jing, Zhu Dapeng, Yu Biao
机构信息
State Key Laboratory of Chemical Biology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, China.
Institute of Translational Medicine, Shanghai Jiao Tong University, Shanghai 200240, China.
出版信息
Org Lett. 2023 Sep 15;25(36):6741-6745. doi: 10.1021/acs.orglett.3c02601. Epub 2023 Aug 30.
The synthesis of neopetrosins A and C, two 2-indolyl -α-d-mannopyranosides, and their congeners has been realized via a direct Ni/photoredox-catalyzed reductive coupling of 3-methoxycarbonyl-2-iodo-1-indoles with pyranosyl bromides.
通过3-甲氧基羰基-2-碘-1-吲哚与吡喃糖基溴的直接镍/光氧化还原催化还原偶联反应，实现了两种2-吲哚基-α-D-甘露吡喃糖苷新岩白菜素A和C及其同系物的合成。
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