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Experimental observations of fractal landscape dynamics in a dense emulsion.

作者信息

Rodríguez-Cruz Clary, Molaei Mehdi, Thirumalaiswamy Amruthesh, Feitosa Klebert, Manoharan Vinothan N, Sivarajan Shankar, Reich Daniel H, Riggleman Robert A, Crocker John C

机构信息

Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, PA, USA.

Department of Physics and Astronomy, James Madison University, Harrisonburg, Virginia, USA.

出版信息

Soft Matter. 2023 Sep 13;19(35):6805-6813. doi: 10.1039/d3sm00852e.

Abstract

Many soft and biological materials display so-called 'soft glassy' dynamics; their constituents undergo anomalous random motions and complex cooperative rearrangements. A recent simulation model of one soft glassy material, a coarsening foam, suggested that the random motions of its bubbles are due to the system configuration moving over a fractal energy landscape in high-dimensional space. Here we show that the salient geometrical features of such high-dimensional fractal landscapes can be explored and reliably quantified, using empirical trajectory data from many degrees of freedom, in a model-free manner. For a mayonnaise-like dense emulsion, analysis of the observed trajectories of oil droplets quantitatively reproduces the high-dimensional fractal geometry of the configuration path and its associated local energy minima generated using a computational model. That geometry in turn drives the droplets' complex random motion observed in real space. Our results indicate that experimental studies can elucidate whether the similar dynamics in different soft and biological materials may also be due to fractal landscape dynamics.

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