Xu Xia, Yang Liming, Cui Yanjun, Hu Bing
College of Science, Gansu Agricultural University No.1, Yingmen Village Lanzhou 730070 P. R. China
RSC Adv. 2023 Aug 30;13(37):25828-25835. doi: 10.1039/d3ra05298b. eCollection 2023 Aug 29.
The successful development of efficient and stable catalysts for 4-NP reduction reactions is beneficial to the environment and ecology. FeO@Pt exhibits excellent catalytic performance for 4-NP reduction reaction due to the synergistic effect between Fe and Pt. But its structure and catalytic performance are extremely unstable. Here, we utilized the small-scale organic compound 2-hydroxyethylamine as surfactant to construct a stable composite nanomaterial. Then investigated the influence of monochromatic light (650 nm, 808 nm and 980 nm) and temperature on the kinetics of 4-NP reduction reaction by 2-hydroxyethylamine stabilized FeO@Pt. The results indicate that both temperature and monochromatic light radiation can affect kinetic regulation. Increasing temperature can promote the catalytic rate, while monochromatic light radiation can induce agglomeration and inhibit the catalytic rate. This study opens up a new way for developing and regulating catalysts for heterogeneous catalysis reactions.
开发高效稳定的4-硝基苯酚还原反应催化剂对环境和生态有益。由于铁和铂之间的协同效应,FeO@Pt对4-硝基苯酚还原反应表现出优异的催化性能。但其结构和催化性能极不稳定。在此,我们利用小分子有机化合物2-羟乙胺作为表面活性剂构建了一种稳定的复合纳米材料。然后研究了单色光(650nm、808nm和980nm)和温度对2-羟乙胺稳定的FeO@Pt催化4-硝基苯酚还原反应动力学的影响。结果表明,温度和单色光辐射均可影响动力学调控。升高温度可促进催化速率,而单色光辐射会导致团聚并抑制催化速率。本研究为开发和调控多相催化反应催化剂开辟了一条新途径。