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空间位阻卟啉中的超分子手性生成:一项批判性理论分析

Supramolecular Chirogenesis in a Sterically Hindered Porphyrin: A Critical Theoretical Analysis.

作者信息

Osadchuk Irina, Luts Hanna-Eliisa, Norvaiša Karolis, Borovkov Victor, Senge Mathias O

机构信息

Department of Chemistry and Biotechnology, Tallinn University of Technology, Akadeemia tee 15, Tallinn, 12618, Estonia.

School of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, Trinity College Dublin, The University of Dublin, 152-160 Pearse Street, Dublin, D02R590, Ireland.

出版信息

Chemistry. 2023 Sep 1;29(49):e202302275. doi: 10.1002/chem.202302275. Epub 2023 Aug 1.

Abstract

Invited for the cover of this issue are the groups of Irina Osadchuk at Tallinn University of Technology and Mathias Senge at Trinity College Dublin. The image depicts how a porphyrin with two guest molecules (R)-camphor sulfonic acid is irradiated with UV-visible light to measure and simulate ECD and UV-Vis spectra. Read the full text of the article at 10.1002/chem.202301408.

摘要

本期的封面文章由塔林理工大学的伊琳娜·奥萨德丘克团队和都柏林圣三一大学的马蒂亚斯·森格团队提供。 该图像描绘了含有两个客体分子(R)-樟脑磺酸的卟啉如何用紫外 - 可见光照射,以测量和模拟电子圆二色光谱(ECD)和紫外 - 可见光谱(UV-Vis)。可在10.1002/chem.202301408阅读该文章的全文。

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