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关于高效室温超声胶体法制备钛酸锶纳米晶体的机理研究。

A mechanistic study on efficient room temperature sonocolloidal obtainment of SrTiO nanocrystals.

作者信息

Mojed Ali, Ashiri Rouholah, Shafyei Ali

机构信息

Department of Materials Engineering, Foulad Institute of Technology, Fouladshahr, Iran.

School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Tehran, Iran.

出版信息

Ultrason Sonochem. 2023 Oct;99:106568. doi: 10.1016/j.ultsonch.2023.106568. Epub 2023 Aug 25.

Abstract

Titanate-based perovskite powders are the most widely used materials for fabrication of multilayered ceramic capacitors and thus are of significant importance. They have been synthesized by two approaches including solid-state and wet chemical processing methods. Synthesis temperature, cost of preparation and quality of synthesized powders are key factors favoring the process. Here, a new ultrasound-assisted precipitation approach is introduced which is able to obtain the quality perovskite nanocrystals such as strontium titanate, barium titanate and so on at room temperature. The obtained powder products were characterized by DTA/TGA, FT-IR, XRD, SEM, EDAX and TEM. The results indicate the room temperature formation of highly pure monosized spherical nanoscale crystals which are loosely agglomerated in nature. It is tried to add the science, mechanism involved in the synthesis and its reaction pattern to the literature along with discussing the cause of low temperature obtainment of the perovskite powder products. The approach described in the current work has the capability to be a general strategy for the synthesis of perovskite materials and essential potentials for large-scale production purposes as it is facile, low temperature and cost-effective.

摘要

钛酸盐基钙钛矿粉末是制造多层陶瓷电容器最广泛使用的材料,因此具有重要意义。它们通过两种方法合成,包括固态法和湿化学处理法。合成温度、制备成本和合成粉末的质量是有利于该工艺的关键因素。在此,引入了一种新的超声辅助沉淀法,该方法能够在室温下获得高质量的钙钛矿纳米晶体,如钛酸锶、钛酸钡等。通过DTA/TGA、FT-IR、XRD、SEM、EDAX和TEM对所得粉末产物进行了表征。结果表明,在室温下形成了高度纯净、单尺寸的球形纳米级晶体,这些晶体在本质上是松散团聚的。在讨论钙钛矿粉末产物低温获得的原因的同时,试图将合成过程中涉及的科学、机理及其反应模式补充到文献中。当前工作中描述的方法有能力成为合成钙钛矿材料的通用策略,并且由于其简便、低温且具有成本效益,具有大规模生产的重要潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4755/10480632/496785476429/ga1.jpg

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