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基于真空沉积的高效且发射可调的无机蓝色钙钛矿发光二极管

High-Efficiency and Emission-Tunable Inorganic Blue Perovskite Light-Emitting Diodes Based on Vacuum Deposition.

作者信息

He Zhiyuan, Peng Chencheng, Guo Runda, Chen Ben, Li Xin, Zhu Xiangyu, Zhang Jian, Liang Wenxi, Wang Lei

机构信息

Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, China.

出版信息

Small. 2024 Jan;20(2):e2305379. doi: 10.1002/smll.202305379. Epub 2023 Sep 1.

Abstract

The fabrication of perovskite light-emitting diodes (PeLEDs) with vacuum deposition shows great potential and commercial value in realizing large-area display panel manufacturing. However, the electroluminescence (EL) performance of vacuum-deposited PeLEDs still lags behind the counterparts fabricated by solution process, especially in the field of blue PeLEDs. Here, the fabrication of high-quality CsPbBr Cl film through tri-source co-evaporation is reported to achieve high photoluminescence quantum yield (PLQY). Compared with the conventional traditional dual-source co-evaporation, the tri-source co-evaporation method allows for freely adjustable elemental ratios, enabling the introduction of the lattice-matched Cs Pb(Br/Cl) phase with the quantum-limited effect into the inorganic CsPb(Br/Cl) emitter. By adjusting the phase distribution, the surface defects of the emitter can be effectively reduced, leading to better blue emission and film quality. Further, the effects of Cs/Pb ratio and Br/Cl ratio on the PLQY and carrier recombination dynamics of perovskite films are investigated. By optimizing the deposition rate of each precursor source, spectrally stable blue PeLEDs are achieved with tunable emission ranging from 468 to 488 nm. Particularly, the PeLEDs with an EL peak at 488 nm show an external quantum efficiency (EQE) of 4.56%, which is the highest EQE value for mixed-halide PeLEDs fabricated by vacuum deposition.

摘要

通过真空沉积制备钙钛矿发光二极管(PeLEDs)在实现大面积显示面板制造方面具有巨大潜力和商业价值。然而,真空沉积的PeLEDs的电致发光(EL)性能仍落后于通过溶液法制备的同类产品,尤其是在蓝色PeLEDs领域。在此,报道了通过三源共蒸发制备高质量的CsPbBrCl薄膜以实现高光致发光量子产率(PLQY)。与传统的双源共蒸发相比,三源共蒸发方法允许自由调节元素比例,能够将具有量子限制效应的晶格匹配的CsPb(Br/Cl)相引入无机CsPb(Br/Cl)发光体中。通过调整相分布,可以有效减少发光体的表面缺陷,从而实现更好的蓝色发射和薄膜质量。此外,研究了Cs/Pb比和Br/Cl比对钙钛矿薄膜的PLQY和载流子复合动力学的影响。通过优化每种前驱体源的沉积速率,实现了光谱稳定的蓝色PeLEDs,其可调发射范围为468至488 nm。特别是,在488 nm处具有EL峰值的PeLEDs表现出4.56%的外量子效率(EQE),这是通过真空沉积制备的混合卤化物PeLEDs的最高EQE值。

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