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碳量子点包覆增强铒掺杂二氧化硅微球的绿色上转换发光

Light Enhancement of Green Up-Conversion Emission from Er-Doped Silica Microspheres by Carbon Quantum Dot Coatings.

作者信息

Do Thuy Chi, Nguyen Thuy Van, Bui Huy, Pham Thanh Binh, Mogilevtsev Dmitry Sergeevich, Le Tuan Tu, Pham Van Hoi

机构信息

Thai Nguyen University of Education, Thai Nguyen University, 20 Luong Ngoc Quyen Rd, Thai Nguyen, 250000, Vietnam.

Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Rd, Hanoi, 100000, Vietnam.

出版信息

J Fluoresc. 2024 Sep;34(5):2003-2008. doi: 10.1007/s10895-023-03420-y. Epub 2023 Sep 4.

Abstract

Combination of high quality cavity such as glass microsphere and emitting nano-particle coating layers can create novel strongly emitting devices. Herein, we demonstrate an erbium-doped silica microsphere coated by dual-emission carbon quantum dots, which have the sizes of 3-5 nm, emitting green up-conversion with narrow line-width green light at wavelength of 537 nm. The dual-emission carbon quantum dots fabricated by hydrothermal process and have luminescent emission wavelengths in the range of 410-550 nm. The carbon quantum dot coated erbium silica microsphere is pumped at wavelength of 976 nm through the optical fibre on which microsphere attached on the tip. The dual-emission carbon quantum dot layers attributed to the strong green up-conversion light enhancement similar coated noble metallic thin films, however the light enhancement from dual-emission carbon quantum dot coated erbium silica microsphere depended on the thickness of coating layers. This result is useful for making visible emitting micro-devices and photonic integrated circuits.

摘要

诸如玻璃微球等高质量腔体与发射纳米颗粒涂层相结合,可以制造出新型的强发射器件。在此,我们展示了一种由双发射碳量子点包覆的掺铒二氧化硅微球,这些碳量子点尺寸为3 - 5纳米,能发射波长为537纳米、线宽较窄的绿色上转换光。通过水热法制备的双发射碳量子点的发光发射波长在410 - 550纳米范围内。碳量子点包覆的铒二氧化硅微球通过光纤在976纳米波长下进行泵浦,微球附着在光纤尖端。双发射碳量子点层产生的强绿色上转换光增强效果类似于包覆的贵金属薄膜,然而双发射碳量子点包覆的铒二氧化硅微球的光增强效果取决于涂层的厚度。这一结果对于制造可见光发射微器件和光子集成电路很有用。

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