Fleetwood Sara K, Bell Sydney, Jetter Reinhard, Foster E Johan
Department of Chemical and Biological Engineering 421, University of British Columbia, 2360 East Mall, Vancouver, BC V6T 1Z3, Canada.
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.
Soft Matter. 2023 Sep 20;19(36):7020-7032. doi: 10.1039/d3sm00720k.
Novel superhydrophobic coatings, that are both biodegradable and biosourced, have the potential to revolutionize the water-repellent coating industry. Here, water-repellent coatings were prepared from commercially unavailable plant waxes, isolated using solvent extraction and characterized using DSC, GC-MS and DLS. In the first stage, a plant survey was conducted to identify an ideal plant source for the final spray, in which Whatman filter paper was submerged in a wax-solvent solution with recrystallization occurring upon air-drying. In the second stage, aqueous, PFC-free wax dispersions were prepared, coated onto textiles (cotton and polyester), and heat-treated with a home drying machine to allow for the spreading and recrystallization of the waxes. In both stages, SEM visualization verified the coating's morphology, and contact angle measurements showed them to be superhydrophobic. It was concluded that, using less coating material than commercial coatings, high-performing petroleum-free coatings could be made and applied onto textiles of various polarities.
新型超疏水涂层兼具生物可降解性和生物源性,有望给防水涂层行业带来变革。在此,利用溶剂萃取法从市场上难以买到的植物蜡制备了防水涂层,并通过差示扫描量热法(DSC)、气相色谱-质谱联用仪(GC-MS)和动态光散射(DLS)对其进行了表征。在第一阶段,进行了一项植物调查,以确定最终喷雾的理想植物来源,其中将沃特曼滤纸浸没在蜡-溶剂溶液中,风干时会发生重结晶。在第二阶段,制备了不含全氟化合物(PFC)的水性蜡分散体,涂覆在纺织品(棉和聚酯)上,并用家用烘干机进行热处理,以使蜡扩散和重结晶。在两个阶段中,扫描电子显微镜(SEM)可视化验证了涂层的形态,接触角测量表明它们具有超疏水性。得出的结论是,使用比商业涂层更少的涂层材料,可以制备出高性能的无石油涂层并应用于各种极性的纺织品上。