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高延性水泥-煅烧煤矸石粉基快速修复材料的制备

Preparation of High-Ductility Cement-Calcined Coal-Gangue-Powder-Composite-Based Rapid Repair Material.

作者信息

Ren Biaokun, Chai Lijuan, Liu Yuanzhen, Wang Yangkai

机构信息

College of Civil Engineering, Taiyuan University of Technology, Taiyuan 030024, China.

出版信息

Materials (Basel). 2023 Sep 3;16(17):6049. doi: 10.3390/ma16176049.

Abstract

Coal gangue is a kind of solid waste. A high-ductility cement-calcined coal-gangue-powder-composite-based rapid repair material (HD-RRM) was prepared by partially replacing cement with calcined coal gangue powder (CCGP) for achieving high ductility and rapid hardening and conforming to the strength requirements of pavement layers. First, the physical and chemical properties and the reactivity of the CCGP were investigated. Second, HD-RRM material was prepared, and its tensile performance characteristic parameters were investigated. Lastly, the hydration products and microstructure of HD-RRM were characterized through tests (e.g., non-evaporable water content, scanning electron microscopy (SEM), X-ray diffraction (XRD), and comprehensive thermogravimetric analysis and differential scanning calorimetry (TG-DSC)). As indicated by the experimental results, the CCGP with a particle size of 1250 mesh exhibited the maximum potential reactivity. The optimal mixing ratio for HD-RRM in the experiments comprised a water-cement ratio of 0.27, a sand-cement ratio of 0.3, a fiber volume fraction of 2%, a cement content of 70%, a CCGP content of 20%, a fly ash (FA) content of 10%, and a superplasticizer content of 0.1%. Using the abovementioned mix design, the prepared HD-RRM was endowed with a 6 h ultimate elongation of 2.75%, an ultimate tensile strength of 7.58 MPa, a compressive strength of 45.4 MPa, and an average crack width of 125.53 μm, which meets the requirements of repair materials and provides a design method for CCGP resource utilization and asphalt concrete road and bridge deck repair.

摘要

煤矸石是一种固体废弃物。通过用煅烧煤矸石粉(CCGP)部分替代水泥,制备了一种高延性水泥-煅烧煤矸石粉-复合材料基快速修复材料(HD-RRM),以实现高延性和快速硬化,并符合路面层的强度要求。首先,研究了CCGP的物理化学性质和反应活性。其次,制备了HD-RRM材料,并研究了其拉伸性能特征参数。最后,通过试验(如非蒸发水含量、扫描电子显微镜(SEM)、X射线衍射(XRD)以及综合热重分析和差示扫描量热法(TG-DSC))对HD-RRM的水化产物和微观结构进行了表征。实验结果表明,粒径为1250目的CCGP表现出最大的潜在反应活性。实验中HD-RRM的最佳配合比为水灰比0.27、砂灰比0.3、纤维体积分数2%、水泥含量70%、CCGP含量20%、粉煤灰(FA)含量10%、高效减水剂含量0.1%。采用上述配合比设计,制备的HD-RRM的6 h极限伸长率为2.75%、极限抗拉强度为7.58 MPa、抗压强度为45.4 MPa、平均裂缝宽度为125.53 μm,满足修复材料的要求,为CCGP资源利用及沥青混凝土路桥面修复提供了一种设计方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f12/10488730/03b4f5f0774f/materials-16-06049-g001a.jpg

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