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模内装饰/微孔注塑成型工艺制备的聚丙烯/纳米碳酸钙/三元乙丙橡胶复合材料的细胞结构与力学性能

The Cellular Structure and Mechanical Properties of Polypropylene/Nano-CaCO/Ethylene-propylene-diene-monomer Composites Prepared by an In-Mold-Decoration/Microcellular-Injection-Molding Process.

作者信息

Zeng Fankun, Liu Xiaorui, Chen Yingxian, Li Hao, Mao Huajie, Guo Wei

机构信息

School of Automotive Engineering, Wuhan University of Technology, Wuhan 430070, China.

Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, China.

出版信息

Polymers (Basel). 2023 Aug 30;15(17):3604. doi: 10.3390/polym15173604.

Abstract

Polypropylene (PP)-composite foams were prepared by a combination process of microcellular injection molding (MIM) and in-mold decoration (IMD). The effect of ethylene propylene diene monomer (EPDM) on the crystallization properties, rheological properties, microstructure, and mechanical properties of PP-composite foams was studied. The effect of the additives on the strength and toughness of PP-composite foam as determined by the multiscale simulation method is discussed. The results showed that an appropriate amount of EPDM was beneficial to the cell growth and toughening of the PP blends. When the content of EPDM was 15 wt%, the PP-composite foams obtained the minimum cellular size, the maximum cellular density, and the best impact toughness. At the same time, the mesoscopic simulation shows that the stress concentration is the smallest, which indicates that 15 wt% EPDM has the best toughening effect in these composite materials.

摘要

通过微孔注塑成型(MIM)和模内装饰(IMD)相结合的工艺制备了聚丙烯(PP)复合泡沫材料。研究了三元乙丙橡胶(EPDM)对PP复合泡沫材料结晶性能、流变性能、微观结构和力学性能的影响。讨论了添加剂对PP复合泡沫材料强度和韧性的影响,并通过多尺度模拟方法进行了测定。结果表明,适量的EPDM有利于PP共混物的泡孔生长和增韧。当EPDM含量为15 wt%时,PP复合泡沫材料的泡孔尺寸最小,泡孔密度最大,冲击韧性最佳。同时,细观模拟表明应力集中最小,这表明15 wt%的EPDM在这些复合材料中具有最佳的增韧效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7ef1/10490399/c35afd628026/polymers-15-03604-g001.jpg

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