Structure and luminescence properties of single-component melilite SrMgSiO:Ce/Tb/Sm for -UV LEDs.

Phosphor-converted white light-emitting diodes (pc-LEDs) have attracted attention in the field of solid-state lighting. Selection and study of suitable single-phase phosphor and packaging modes are currently the main research hotspots. Herein, color-tunable photoluminescence (PL) and thermally stable tri-doped Melitite SrMgSiO:Ce/Tb/Sm are systematically studied structural and static/dynamic spectral analyses. All dopants could only be accommodated in the Sr site due to similar ionic radii. Previous studies have concluded that green and red PL could be obtained from singly doped Tb and Sm phosphors with excellent reproduction, and color tunable PL can be achieved from Ce/Tb co-doped phosphors. The forbidden 4f-4f transitions of Tb/Sm cause low efficiency and Ce/Tb co-doping cannot achieve white light emissions. Alternatively, co-doping allowed 5d-4f transition sensitizer with emissions in the UV-blue region (, Ce), color-tunable PL (including the white light); high efficiency of SrMgSiO:Ce/Tb/Sm could be achieved energy transfer (ET) from Ce → Tb → Sm. The impossibly direct ET from Ce → Sm is associated with the side metal-metal charge transfer (MMCT) effect. Due to chemically nonequivalent substitutions, two positive Ce(Tb,Sm) and one negative V'' were created to maintain the whole charge balance. To reduce the defects and allow more dopants to enter into the Sr site, Na was added as a charge balancer to enhance PL efficiency. Furthermore, an alkaline-earth-metal-ions blending strategy partial replacement of Sr with Ba was investigated to regulate PL owing to the change in crystal field splitting. PL blue-shifted by Ba-co-doping, which could increase the degree of overlapping and enhance ET efficiency. As a proof-of-concept experiment, the pc-LED fabricated a combination of the optimal Sr(Ba)MgSiO:Ce/Tb/Sm/Na and an -UV LED chip based on a remote 'capping' packaging mode shows excellent performances, indicating its strong potential application in the field of solid-state lighting.