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基于硼酸和席夫碱的荧光传感器用于检测牛奶和牛血清白蛋白样品中的L-色氨酸。

Boric acid and Schiff base-based fluorescent sensor for detection of L-tryptophan in milk and BSA samples.

作者信息

Duru Kamaci Ümran, Kamaci Musa

机构信息

Department of Chemistry, Faculty of Arts and Sciences, Yıldız Technical University, İstanbul, Turkey.

Piri Reis University, İstanbul, Turkey.

出版信息

Turk J Chem. 2022 Feb 28;46(3):929-940. doi: 10.55730/1300-0527.3381. eCollection 2022.

Abstract

In the present paper, the fluorescence sensor based on Schiff base and boric acid was developed for easy and rapid detection of L-tryptophan in different samples such as milk and bovine serum albumin. The photoluminescence intensity was measured by using fluorescent measurements and the results indicated that the developed fluorescent sensor was exhibited selective, sensitive, reliable determination against L-tryptophan, and a series of various analytes such as cations, amino acids, and organic compounds were used to investigate the selectivity of the fluorescent chemosensor. The limit of detection and linear range of the chemosensor were calculated as 0.82 μM, and 0.1-500 μM, respectively. The performance of the chemosensor was evaluated in terms of selectivity, reversible usage, stability, and interference/anti-interference. The developed chemosensor was exhibited excellent photostability, and it was a great potential application of L-tryptophan in bovine serum albumin and milk samples.

摘要

在本论文中,基于席夫碱和硼酸开发了一种荧光传感器,用于简便快速地检测牛奶和牛血清白蛋白等不同样品中的L-色氨酸。通过荧光测量来测定光致发光强度,结果表明所开发的荧光传感器对L-色氨酸具有选择性、灵敏且可靠的测定能力,并且使用了一系列各种分析物(如阳离子、氨基酸和有机化合物)来研究荧光化学传感器的选择性。该化学传感器的检测限和线性范围分别计算为0.82 μM和0.1 - 500 μM。从选择性、可逆使用性、稳定性以及干扰/抗干扰性方面对该化学传感器的性能进行了评估。所开发的化学传感器表现出优异的光稳定性,并且在牛血清白蛋白和牛奶样品中对L-色氨酸具有很大的潜在应用价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0881/10503980/8fa1d58fc4c4/turkjchem-46-3-929f1.jpg

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