Kazan-Kaya Emine Sena, Bayramoğlu Mahmut
Department of Chemical Engineering, Faculty of Engineering, Gebze Technical University, Kocaeli, Turkey.
Turk J Chem. 2022 Nov 29;47(1):196-206. doi: 10.55730/1300-0527.3529. eCollection 2023.
In this paper, ceria (CeO) nanorod (NR) supported Ni-CrO anode electrocatalysts were synthesized as nonnoble metal-based anode electrocatalysts for ethanol electrooxidation reaction (EOR) in alkaline media. Physicochemical characterization of the electrocatalysts was investigated by XRD, SEM, and TEM techniques. Electrochemical performances of the catalysts were investigated via cyclic voltammetry (CV), linear sweep voltammetry (LSV), and chronoamperometry (CA) techniques. The data from linear LSV were used for the diffusion coefficient of the electrocatalysts. The CA experiments' results showed the tolerance for catalytic poisoning and durability of the synthesized electrocatalysts.
本文合成了二氧化铈(CeO)纳米棒(NR)负载的Ni-CrO阳极电催化剂,作为用于碱性介质中乙醇电氧化反应(EOR)的非贵金属基阳极电催化剂。通过XRD、SEM和TEM技术对电催化剂进行了物理化学表征。通过循环伏安法(CV)、线性扫描伏安法(LSV)和计时电流法(CA)技术研究了催化剂的电化学性能。线性LSV的数据用于计算电催化剂的扩散系数。CA实验结果表明了合成电催化剂对催化中毒的耐受性和耐久性。