Bridging Effect of Carbon Nitride with More Negative Conduction Potential and Halogens Promotes the Liquid-Phase Oxidation of Aromatic C-H Bonds.

The selective oxidation of benzyl C-H bonds of alkyl aromatic hydrocarbons under solvent-free conditions by using heterogeneous catalysis is a challenging task. In this work, we designed a carbon nitride photocatalyst with a high charge separation efficiency and a directed charge transfer path, which was doped with Ni and Br in the carbon nitride skeleton. Br was deposited directionally onto the electron-rich Ni surface traps to form a bond with Ni, which acted as a charge transfer bridge connecting CN and Br, resulting in a bridging effect. Photogenerated electrons were transferred from Ni target to Br, and electrons were aggregated to form a directional charge transfer path, thereby enhancing the photocatalytic performance of CN. The photocatalyst was utilized for the selective oxidation of ethylbenzene at room temperature, atmospheric pressure, and solvent-free conditions. Under batch conditions simulating solar irradiation, the conversion of ethylbenzene was 43.3% and the selectivity of the product acetophenone was up to 92.0%. With the continuous flow strategy, the conversion of ethylbenzene was increased to 52.4 and 48.1%, respectively, while the selectivity reached 92.7 and 91.0%, and the reaction time was reduced from 24 to 2.1 h. The catalyst was also found to be broadly applicable for the selective oxidation of C-H bonds in the benzyl position of alkyl aromatic hydrocarbons.