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Eu 激活 SrGaO 荧光粉的力学发光和光致发光性能。

Mechanoluminescence and photoluminescence properties of Eu -activated SrGa O phosphors.

机构信息

Post Graduate Department of Physics, All Saints' College, University of Kerala, Thiruvananthapuram, Kerala, India.

Post Graduate Department of Physics and Research Centre, Mahatma Gandhi College, University of Kerala, Thiruvananthapuram, India.

出版信息

Luminescence. 2024 Jan;39(1):e4602. doi: 10.1002/bio.4602. Epub 2023 Oct 24.

Abstract

Red-emitting Eu activated SrGa O phosphors were synthesized using a conventional solid-state reaction method. The structural, optical, and luminescence properties were systematically investigated. The synthesized phosphors are single phase with a monoclinic structure. There are no significant changes in the phase and the crystal structure of the host matrix after incorporating Eu ions. The undoped and Eu doped SrGa O phosphors exhibited good mechanoluminescence (ML) emission without any irradiation with ultraviolet (UV) or gamma rays. Eu -activated SrGa O phosphors have prominent red emission attributed to D  →  F forced electric dipole transition excited at 395 nm. The colour coordinates and purity of the SrGa O : 0.08 Eu phosphor were calculated to be (0.6102, 0.3810) and 97.6%, respectively. The quantum efficiency is 12.68%, and was better than that of commercially available red phosphors. The ML and photoluminescence studies revealed that the synthesized phosphors can act as potential candidates for stress sensors, UV or near-UV light-emitting diodes (NUV LEDs) and components of phosphor-converted white light-emitting diode (pc-WLED) applications.

摘要

红色发射的 Eu 激活 SrGaO 荧光粉是采用传统的固态反应法合成的。系统地研究了它们的结构、光学和发光性能。合成的荧光粉为单相单斜结构。掺入 Eu 离子后,基质的相和晶体结构没有明显变化。未掺杂和 Eu 掺杂的 SrGaO 荧光粉在没有紫外线(UV)或伽马射线辐照的情况下表现出良好的力学发光(ML)发射。Eu 激活的 SrGaO 荧光粉具有显著的红色发射,归因于在 395nm 处激发的 D  →  F 强迫电偶极跃迁。SrGaO:0.08Eu 荧光粉的色坐标和纯度分别计算为(0.6102,0.3810)和 97.6%。量子效率为 12.68%,优于市售红色荧光粉。ML 和光致发光研究表明,合成的荧光粉可用作潜在的应力传感器、紫外或近紫外发光二极管(NUV LEDs)以及磷光转换白光发光二极管(pc-WLED)组件的候选材料。

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