Department of Chemical and Materials Engineering, National Central University, Jhongli, 320, Taiwan, ROC.
Department of Chemical Engineering, National Taiwan University, Taipei, 106, Taiwan, ROC.
Chemosphere. 2023 Dec;343:140266. doi: 10.1016/j.chemosphere.2023.140266. Epub 2023 Sep 23.
Heavy metal ions are toxic to humans, plants, and marine life, making it crucial to eliminate them from water. This study reports the development of a new nanocomposite material (Alg@Ag/PU) that involves modifying silver nanoparticles (Ag NPs) with alginate (Alg) and coating them onto a polyurethane sponge (PU) for removing heavy metal ions. The successful coating of Alg@Ag NPs onto PU due to their strong chemical binding was confirmed by morphology and size characterization. Batch experiments were conducted to evaluate the removal efficiency of heavy metal ions at high concentrations (∼100 mg/L). The maximum adsorption amount was achieved within 6 h, and the highest removal efficiency was obtained at pH values between 6 and 7. Furthermore, the Alg@Ag/PU nanocomposite demonstrated excellent recyclability for metal ion removal even after 5 cycles. In summary, this work developed a simple and cost-effective method for producing an environmentally-friendly nanocomposite material for the efficient removal of heavy metal ions.
重金属离子对人类、植物和海洋生物都具有毒性,因此将其从水中去除至关重要。本研究报告了一种新型纳米复合材料(Alg@Ag/PU)的开发,该材料涉及用藻酸盐(Alg)修饰银纳米粒子(Ag NPs),并将其涂覆到聚氨酯海绵(PU)上,以去除重金属离子。通过形态和尺寸特征证实了 Alg@Ag NPs 由于其强化学结合而成功涂覆到 PU 上。进行了批量实验以评估高浓度(约 100mg/L)下重金属离子的去除效率。在 6 小时内达到最大吸附量,在 pH 值在 6 到 7 之间时获得了最高的去除效率。此外,Alg@Ag/PU 纳米复合材料即使经过 5 次循环也表现出优异的金属离子去除可循环性。总之,这项工作开发了一种简单且具有成本效益的方法,用于生产环保型纳米复合材料,以有效去除重金属离子。