Yang Jun, Cai Wenjin, Rizwan Khan Mohammad, Ahmad Naushad, Zhang Zhengke, Meng Lanhuan, Zhang Wanli
School of Food Science and Engineering, Hainan University, Haikou 570228, China.
Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
Foods. 2023 Sep 6;12(18):3336. doi: 10.3390/foods12183336.
In this work, the role of tannic acid (TA) and Fe in crosslinking pectin (PE) to enhance its physicochemical properties was investigated. Specifically, PE/TA/Fe composite films were prepared using the solution casting method, and the UV-blocking properties, transparency, water content, physico-mechanical properties, antioxidant properties and degradability of the PE composite films were investigated. The microstructure of the PE composite films and the interactions between the contained components were analyzed using FTIR, X_crystal diffraction and SEM scanning electron microscopy. The results showed that the addition of TA and Fe can significantly improve the UV barrier properties and antioxidant properties of PE films. Meanwhile, Fe could form a metal phenol network with TA and crosslink with the PE film, which makes the structure of the PE film denser and thus significantly reduces the water vapor permeability of the PE film. In addition, this work also indicated that the PE composite coatings have a favorable preservation effect on passion fruit, which leads to the lowest weight loss rate and wrinkle index of the passion fruit within 7 days of storage and shows good appearance quality and commercial value. This work indicates that the addition of tannic acid and Fe significantly improved the mechanical and barrier properties of pectin films, and the composite pectin coating extended the shelf life of passion fruit.
在这项工作中,研究了单宁酸(TA)和铁在交联果胶(PE)以增强其物理化学性质方面的作用。具体而言,采用溶液浇铸法制备了PE/TA/Fe复合薄膜,并对PE复合薄膜的紫外线阻隔性能、透明度、含水量、物理机械性能、抗氧化性能和降解性进行了研究。利用傅里叶变换红外光谱(FTIR)、X射线晶体衍射和扫描电子显微镜(SEM)对PE复合薄膜的微观结构及其所含成分之间的相互作用进行了分析。结果表明,添加TA和铁可以显著提高PE薄膜的紫外线阻隔性能和抗氧化性能。同时,铁可以与TA形成金属酚网络并与PE薄膜交联,这使得PE薄膜的结构更加致密,从而显著降低了PE薄膜的水蒸气透过率。此外,这项工作还表明,PE复合涂层对百香果具有良好的保鲜效果,在储存7天内百香果的失重率和皱纹指数最低,呈现出良好的外观品质和商业价值。这项工作表明,添加单宁酸和铁显著改善了果胶薄膜的机械性能和阻隔性能,复合果胶涂层延长了百香果的货架期。