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通过热处理提高用于含金刚石工具的金属基复合材料的耐磨性能

Improvement in Abrasive Wear Resistance of Metal Matrix Composites Used for Diamond-Impregnated Tools by Heat Treatment.

作者信息

Cygan-Bączek Elżbieta, Cygan Sławomir, Wyżga Piotr, Novák Pavel, Lapčák Ladislav, Romański Andrzej

机构信息

Łukasiewicz Research Network-Krakow Institute of Technology, Zakopiańska 73 Str., 30-418 Krakow, Poland.

Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic.

出版信息

Materials (Basel). 2023 Sep 13;16(18):6198. doi: 10.3390/ma16186198.

Abstract

This work presents the possibilities of producing a substitute for a commercial matrix material for sintered metal-diamond tools which is characterized by increased tribological properties required in machining natural stones and concrete. In this study, the improvement in wear behavior of sintered pre-alloyed matrix caused by a thermal treatment was investigated. Several mixtures made of commercially available powders were homogenized by ball milling and consolidated at 900 °C using the spark plasma sintering (SPS) method. During cooling down, the specimens were subjected to isothermal holding at 350 or 250 °C for 1 h. After consolidation, all specimens were tested for density and hardness, whereas selected specimens were characterized by scanning electron microscopy (SEM) and flexural strength tests. The specimens made of BDCM50 powder (a mixture of the base and pre-alloyed powders in 50:50 proportion) shows excellent properties including σ = 1045 MPa in the three-point bending test and HV10 ≈ 380. Resistance to abrasive wear evaluated in both three-body and two-body conditions in the MWT abrasion test was estimated at Ai3=18.1±3.9 μm/20 m and Ai2=95.9±11.8 μm/20 m, respectively. A series of diamond-impregnated specimens (segments) was also produced and tested for wear rate on abrasive concrete. The potential graphitization of the diamond grits was investigated using Raman spectroscopy and X-ray diffraction. As a reference, both the base Fe-Mn-Cu-Sn-C and commercially available Co+20%WC alloy were used to compare selected properties of the investigated materials. It has been proved that heat-treated specimens made of the base mixture modified with pre-alloyed powders are characterized by increased hardness and resistance to abrasive wear. The BDCM50 matrix has a negligible effect on diamond graphitization and shows excellent field performance, which makes it a good potential substitute for replacing Co+20%WC in sintered diamond-impregnated tools.

摘要

这项工作展示了生产一种用于烧结金属金刚石工具的商业基体材料替代品的可能性,该替代品的特点是具有加工天然石材和混凝土所需的增强摩擦学性能。在本研究中,研究了热处理对烧结预合金基体磨损行为的改善情况。由市售粉末制成的几种混合物通过球磨进行均质化处理,并使用放电等离子烧结(SPS)方法在900℃下固结。在冷却过程中,试样在350或250℃下等温保持1小时。固结后,对所有试样进行密度和硬度测试,而选定的试样则通过扫描电子显微镜(SEM)和抗弯强度测试进行表征。由BDCM50粉末(基体粉末和预合金粉末按50:50比例混合)制成的试样表现出优异的性能,包括三点弯曲试验中的σ = 1045 MPa和HV10≈380。在MWT磨损试验中,在三体和二体条件下评估的抗磨粒磨损性能分别估计为Ai3 = 18.1±3.9μm/20 m和Ai2 = 95.9±11.8μm/20 m。还制备了一系列含金刚石的试样(刀头),并在磨蚀性混凝土上测试了磨损率。使用拉曼光谱和X射线衍射研究了金刚石磨粒的潜在石墨化情况。作为参考,使用基体Fe-Mn-Cu-Sn-C和市售的Co + 20%WC合金来比较所研究材料的选定性能。事实证明,用预合金粉末改性的基体混合物制成的热处理试样具有更高的硬度和抗磨粒磨损性能。BDCM50基体对金刚石石墨化的影响可忽略不计,并表现出优异的现场性能,这使其成为在烧结含金刚石工具中替代Co + 20%WC的良好潜在替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6767/10532835/95c4a73fe680/materials-16-06198-g001.jpg

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