Manipulating the Cathodic Modification Effect on Corrosion Resistance of High Corrosion-Resistant Titanium Alloy.

Further improving the corrosion resistance of the ASTM Grade 13 (Gr13) titanium alloy was achieved by manipulating the cathodic modification effect. The cathodic modification of Gr13 was mainly related to the TiNi precipitate, where minor Ru was contained and controlled the precipitate in terms of size and distribution, which could manipulate the cathodic modification effect. Parameters such as temperature and cooling rate during the recrystallization process were designed to control precipitation behavior, where the temperature at 850 °C was selected to allow the full dissolution of the TiNi precipitate. The cooling rate, as high as 160.9 °C/min, was still enough for precipitation to occur during the cooling stage, leading to the formation of the TiNi precipitate along with a grain boundary. The cooling rate of water quenching was too fast to cause the diffusion process, resulting in a large amount of the β-Ti phase without the precipitate, which was pre-formed while heated at 850 °C. Aging at 600 °C caused the re-precipitation of TiNi, and, at that moment, the precipitate was refined and separated, as a good aspect of the catalyst for HER. Therefore, the aged sample after water quenching showed the lowest onset potential for HER with the highest corrosion potential, indicating that its passivation ability was improved by the strengthened cathodic modification effect. This improvement was confirmed by the OCP results, where passivation survival was observed for the aged sample due to the highest cathodic modification effect. Therefore, the aged sample, which had refined and separate precipitates, showed the lowest corrosion rate.