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木材-聚(糠醇)预浸料:一种新型环保层压复合材料。

Wood-Poly(furfuryl Alcohol) Prepreg: A Novel, Ecofriendly Laminate Composite.

作者信息

Acosta Andrey Pereira, Esteves Bruno, Cruz Joziel Aparecido da, Aramburu Arthur Behenck, Kairytė Agnė, Członka Sylwia, Ramos Dionatan Orestes, Goularte Matheus de Paula, Delucis Rafael de Avila, Gatto Darci Alberto, Amico Sandro Campos

机构信息

Postgraduate Program in Mining, Metallurgical and Materials Engineering, Federal University of Rio Grande Do Sul, Porto Alegre 90040-060, RS, Brazil.

Department of Wood Engineering, Polytechnic Institute of Viseu, Av. Cor. José Maria Vale de Andrade, 3504-510 Viseu, Portugal.

出版信息

Materials (Basel). 2023 Sep 15;16(18):6237. doi: 10.3390/ma16186237.

Abstract

Prepregs are commonly fabricated with non-renewable petroleum-based materials. To reduce the impact of the manufacturing of these materials and to produce more sustainable prepregs, this research aims to manufacture poly(furfuryl alcohol)/wood veneer prepregs and their posterior molding in laminate composites. For this purpose, the vacuum infusion process was used to impregnate the wood veneers, and compression molding was applied to manufacture three- and four-layer laminate composites. Scanning electronic microscopy was used to evaluate the impregnation. the laminate manufacturing and differential scanning calorimetry were used to predict the shelf-life of the prepregs, Fourier-transform infrared was used to evaluate the induced hydrolysis resistance, and thermogravimetric analysis was used to determine the thermal degradation of the laminates. Moreover, water uptake and flexural, compressive, and tensile properties were evaluated. The kinetic models were effective and showed a shelf life for the laminates of approximately 30 days in storage at -7 °C, which is an interesting result for laminates with lignocellulosic materials. FTIR proved the laminates' excellent resistance to hydrolysis. The water absorption, thermal stability, and mechanical properties did not differ as the amount of wood veneer increased, but these results were up to ~40% higher compared with unidirectional wood laminates found in the literature, which is probably linked to the excellent interface observed with SEM.

摘要

预浸料通常由不可再生的石油基材料制成。为了减少这些材料制造过程中的影响并生产更可持续的预浸料,本研究旨在制造聚糠醇/木单板预浸料及其在层压复合材料中的后续成型。为此,采用真空灌注工艺浸渍木单板,并采用压缩成型工艺制造三层和四层层压复合材料。使用扫描电子显微镜评估浸渍情况。利用层压板制造和差示扫描量热法预测预浸料的保质期,利用傅里叶变换红外光谱评估诱导水解抗性,并利用热重分析确定层压板的热降解情况。此外,还评估了吸水性以及弯曲、压缩和拉伸性能。动力学模型是有效的,结果表明层压板在-7℃储存时的保质期约为30天,这对于含有木质纤维素材料的层压板来说是一个有趣的结果。傅里叶变换红外光谱证明层压板具有优异的抗水解性能。随着木单板用量的增加,吸水率、热稳定性和机械性能没有差异,但与文献中报道的单向木质层压板相比,这些结果高出约40%,这可能与扫描电子显微镜观察到的优异界面有关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e528/10532720/b2b372a1ba15/materials-16-06237-g001.jpg

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