Wang Xi, Shen Xinpu
Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China.
Institute of Reservoir Engineering, College of Petroleum Engineering, China University of Petroleum (Huadong), Qingdao 266580, China.
Materials (Basel). 2023 Sep 19;16(18):6280. doi: 10.3390/ma16186280.
After the Fukushima nuclear accident, the development of new accident-tolerant fuel cladding materials has become a research hotspot around the world. Due to its outstanding corrosion resistance, radiation resistance, and creep properties at elevated temperatures, the oxide dispersion strengthened (ODS) FeCrAl alloy, as one of the most promising candidate materials for accident-tolerant fuel cladding, has been extensively studied during the past decade. Recent research on chemical composition design as well as its effects on the microstructure and mechanical properties has been reviewed in this paper. In particular, the reasonable/optimized content of Cr is explained from the aspects of oxidation resistance, radiation resistance, and thermal stability. The essential role of the Al element in oxidation resistance, high-temperature stability, and workability was reviewed in detail. The roles of oxide-forming elements, i.e., Y (YO), Ti, and Zr, and the solid solution strengthening element, i.e., W, were discussed. Additionally, their reasonable contents were summarized. Typical types of oxide, i.e., Y-Ti-O, Y-Al-O, and Y-Zr-O, and their formation mechanisms were also discussed in this paper. All aspects mentioned above provide an important reference for understanding the effects of composition design parameters on the properties of nuclear-level ODS FeCrAl alloy.
福岛核事故后,新型耐事故燃料包壳材料的研发成为全球研究热点。由于其在高温下具有出色的耐腐蚀性、抗辐射性和蠕变性能,作为耐事故燃料包壳最有前景的候选材料之一,氧化物弥散强化(ODS)FeCrAl合金在过去十年中得到了广泛研究。本文综述了近期关于化学成分设计及其对微观结构和力学性能影响的研究。特别从抗氧化性、抗辐射性和热稳定性方面解释了Cr的合理/优化含量。详细综述了Al元素在抗氧化性、高温稳定性和加工性能方面的重要作用。讨论了氧化物形成元素Y(YO)、Ti和Zr以及固溶强化元素W的作用。此外,总结了它们的合理含量。本文还讨论了典型的氧化物类型,即Y-Ti-O、Y-Al-O和Y-Zr-O及其形成机制。上述各方面为理解成分设计参数对核级ODS FeCrAl合金性能的影响提供了重要参考。