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添加废弃物制备可生物降解聚合物复合材料

Production of Biodegradable Polymeric Composites with the Addition of Waste.

作者信息

da Silva Fernandes Fernando Antonio, Serra Juan Carlos Valdés, de Oliveira Costa Dayriane do Socorro, Martin Camilo Andrés Guerrero

机构信息

Department of Engineering (FAE), Campus Salinópolis, Federal University of Pará, Rua Raimundo Santana Cruz, S/N, Bairro São Tomé, Salinópolis 68721-000, PA, Brazil.

Laboratory of Composite Materials, Federal University of Tocantins, Quadra 109 Norte Ave. NS-15, ALCNO-14, Master Plan Norte, Palmas 77001-090, TO, Brazil.

出版信息

Materials (Basel). 2023 Sep 20;16(18):6305. doi: 10.3390/ma16186305.

Abstract

Several solutions have been presented to minimize the environmental impact generated by polymers produced from petroleum resources. This work produced a biopolymer using glycerol, starch (<5) and macaúba epicarp fiber (10-15-20-25-30%) as reinforcement. The interaction of glycerol with starch was favored by the addition of acetic acid (CHCOOH). The pH was adjusted with sodium hydroxide (NaOH) at a concentration of 0.1 mol·L. The characterization was carried out through scanning electron microscopy (SEM), infrared reflectance-FTIR, water solubility, biodegradability and technological properties. Through the results obtained in this work, it is observed that the tensile strength and modulus of elasticity are influenced by the addition of the fiber concentration; the sample that received a 30% addition presented 19.17 MPa and 348.12 MPa, respectively. All samples showed low solubility in water and low density, in addition to a high rate of degradability in soil with mass loss corresponding to 59% over a period of three months. The results of this investigation are satisfactory for the production of materials that can be used in everyday life, replacing conventional plastic.

摘要

已经提出了几种解决方案,以尽量减少石油资源生产的聚合物对环境的影响。这项工作使用甘油、淀粉(<5)和马卡巴果皮纤维(10%-15%-20%-25%-30%)作为增强材料制备了一种生物聚合物。添加乙酸(CHCOOH)有利于甘油与淀粉的相互作用。用浓度为0.1 mol·L的氢氧化钠(NaOH)调节pH值。通过扫描电子显微镜(SEM)、红外反射-FTIR、水溶性、生物降解性和工艺性能进行表征。通过这项工作获得的结果可以观察到,拉伸强度和弹性模量受纤维浓度添加量的影响;添加量为30%的样品分别呈现出19.17 MPa和348.12 MPa。所有样品在水中的溶解度低且密度小,此外在土壤中的降解率高,在三个月的时间内质量损失达到59%。这项研究的结果对于生产可用于日常生活、替代传统塑料的材料来说是令人满意的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/707e/10532791/64355b14c2f8/materials-16-06305-g001.jpg

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