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基于Pd/WO的兼具化学电阻和气致变色响应的混合氢传感器。

Hybrid Hydrogen Sensor Based on Pd/WO Showing Simultaneous Chemiresistive and Gasochromic Response.

作者信息

Kim Sanghoon, Maeng Bohee, Yang Yijun, Kim Kwanwoo, Jung Daewoong

机构信息

Advanced Mechatronics R&D Group, Korea Institute of Industrial Technology (KITECH), Daegu 42994, Republic of Korea.

出版信息

Nanomaterials (Basel). 2023 Sep 15;13(18):2563. doi: 10.3390/nano13182563.

DOI:10.3390/nano13182563
PMID:37764592
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10536676/
Abstract

The gasochromism of WO, wherein the color of the material changes according to the reaction of gas, can immediately allow for the determination of the presence of hydrogen by the naked eye. We have also developed a hybrid hydrogen sensor for WO, a metal oxide, that can simultaneously utilize its gasochromic response and resistance to hydrogen. Because the proposed sensor has a transparent electrode on a glass substrate, it is a structure that can not only reveal the change in resistance but also more clearly illustrate the gasochromic response. A hybrid sensing demonstration in a hydrogen leak environment was successfully performed to verify a sensor that was capable of utilizing the resistive and gasochromic response of WO.

摘要

WO₃的气致变色现象,即材料的颜色会根据气体的反应而变化,可通过肉眼立即确定氢气的存在。我们还开发了一种用于金属氧化物WO₃的混合氢传感器,它可以同时利用其气致变色响应和对氢气的电阻特性。由于所提出的传感器在玻璃基板上有一个透明电极,它不仅可以显示电阻的变化,还能更清楚地说明气致变色响应。在氢气泄漏环境中成功进行了混合传感演示,以验证一种能够利用WO₃的电阻和气致变色响应的传感器。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/823b/10536676/179024646e1c/nanomaterials-13-02563-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/823b/10536676/7bb2050fe3f2/nanomaterials-13-02563-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/823b/10536676/179024646e1c/nanomaterials-13-02563-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/823b/10536676/7bb2050fe3f2/nanomaterials-13-02563-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/823b/10536676/179024646e1c/nanomaterials-13-02563-g004.jpg

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本文引用的文献

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Large-Area Printed Oxide Film Sensors Enabling Ultrasensitive and Dual Electrical/Colorimetric Detection of Hydrogen at Room Temperature.大面积印刷氧化物薄膜传感器可实现室温下对氢气的超高灵敏度和双电/比色检测。
ACS Sens. 2023 Aug 25;8(8):3004-3013. doi: 10.1021/acssensors.3c00469. Epub 2023 Jul 24.
2
Design and Fabrication Challenges of a Highly Sensitive Thermoelectric-Based Hydrogen Gas Sensor.基于热电效应的高灵敏度氢气传感器的设计与制造挑战
Micromachines (Basel). 2019 Sep 27;10(10):650. doi: 10.3390/mi10100650.
3
Self-Assembled Hierarchical Interfaces of ZnO Nanotubes/Graphene Heterostructures for Efficient Room Temperature Hydrogen Sensors.
用于高效室温氢气传感器的 ZnO 纳米管/石墨烯杂化结构的自组装分级界面。
ACS Appl Mater Interfaces. 2017 Apr 5;9(13):12064-12072. doi: 10.1021/acsami.7b00338. Epub 2017 Mar 27.