Ulfat Wajad, Mohyuddin Ayesha, Amjad Muhammad, Othman Mohd Hafiz Dzarfan, Gikas Petros, Kurniawan Tonni Agustiono
Department of Chemistry, University of Management and Technology, Lahore, 54770, Pakistan.
Department of Chemistry, University of Management and Technology, Lahore, 54770, Pakistan.
J Environ Manage. 2023 Dec 1;347:119129. doi: 10.1016/j.jenvman.2023.119129. Epub 2023 Sep 29.
Buffing dust, generated from tannery industries, is a source of air pollution in Pakistan. Valorization of the waste into another useful material is important to deal with the environmental pollution, while reducing waste disposal costs in landfills. To demonstrate its technological strength, this work fabricates a thermal insulation material made of plaster of Paris and the buffing dust (from tanning waste) in the form of a composite with superior mechanical properties and low thermal conductivity. Buffing dust with concentrations ranging from 5 to 20% (w/w) were loaded in the composite. The samples synthesized were made slurry of plaster of Paris, buffing dust, and water at ambient temperature. The physico-mechanical properties of composite were analyzed. It was found that the composite had better thermal insulation properties than the panels of the plaster of Paris. Its thermal conductivity was reduced to 15% after adding buffing dust (20% w/w). All the materials had physico-chemical properties like tensile strength (0.02 MPa and 0.06 MPa), density (700-400 kg/m), water absorption (5.2-8.6%) and thermal conductivity (0.17000-0.09218 W/m-K). Thermogravimetric analysis showed that the material was thermally stable at temperatures ranging from 145 to 177 °C, while FT-IR results revealed that the composite contained O-H, N-H, and CO functional groups. SEM analysis displayed that the composite's homogeneity was reduced with low voids due to buffing dust addition, while EDX analysis showed that the composite contained 23.62% of S, 26.76% of Ca, 49.2% of O and 0.42% of C. This implies that buffing dust could be recycled to manufacture heat insulation materials for construction sector to reduce air pollution, while minimizing energy consumption. By integrating the buffing dust from tanning waste and the plaster of Paris as a composite for construction sector, this work promotes the recycling of unused waste, while saving public funds. Instead of paying landfill fees and polluting soil, the waste may be recycled at lower cost, while reducing environmental damage.
制革行业产生的打磨粉尘是巴基斯坦空气污染的一个来源。将这种废弃物转化为另一种有用材料对于应对环境污染很重要,同时还能降低垃圾填埋场的废物处理成本。为展示其技术实力,本研究制作了一种由巴黎石膏和(来自制革废料的)打磨粉尘制成的隔热材料,其形式为一种具有优异机械性能和低导热率的复合材料。复合材料中加入了浓度为5%至20%(重量/重量)的打磨粉尘。合成的样品在环境温度下由巴黎石膏、打磨粉尘和水制成浆料。对复合材料的物理机械性能进行了分析。结果发现,该复合材料比巴黎石膏板具有更好的隔热性能。添加打磨粉尘(20%重量/重量)后,其导热率降低至15%。所有材料都具有诸如拉伸强度(0.02兆帕和0.06兆帕)、密度(700 - 400千克/立方米)、吸水率(5.2 - 8.6%)和导热率(0.17000 - 0.09218瓦/米·开尔文)等物理化学性质。热重分析表明,该材料在145至177摄氏度的温度范围内热稳定,而傅里叶变换红外光谱结果显示该复合材料含有O - H、N - H和CO官能团。扫描电子显微镜分析显示,由于添加了打磨粉尘,复合材料的均匀性降低且孔隙率低,而能谱分析表明该复合材料含有23.62%的硫、26.76%的钙、49.2%的氧和0.42%的碳。这意味着打磨粉尘可以被回收利用来制造建筑行业的隔热材料,以减少空气污染,同时将能源消耗降至最低。通过将制革废料中的打磨粉尘与巴黎石膏整合为一种用于建筑行业的复合材料,本研究促进了未使用废料的回收利用,同时节省了公共资金。与其支付垃圾填埋费用并污染土壤,这些废料可以以较低成本进行回收利用,同时减少对环境的破坏。