双（蒽）铜酸盐二价阴离子二钾盐[K（四氢呋喃）][{Cu（9,10-η-蒽）}]的晶体结构与合成，首个铜的阴离子芳烃配合物
Crystal structure and synthesis of the bis(anthracene)dicuprate dianion as the dipotassium salt, [K(tetrahydrofuran)][{Cu(9,10-η-anthracene)}], the first anionic arene complex of copper.
作者信息
Young Victor G, Brennessel William W, Ellis John E
机构信息
Department of Chemistry, 207 Pleasant Street SE, University of Minnesota, Minneapolis, MN 55455, USA.
Department of Chemistry, 120 Trustee Road, University of Rochester, Rochester, NY 14627, USA.
出版信息
Acta Crystallogr C Struct Chem. 2023 Nov 1;79(Pt 11):456-463. doi: 10.1107/S2053229623008367. Epub 2023 Oct 3.
Reactions of (tricyclohexylphosphane)copper(I) chloride with two equivalents of potassium anthracene (KAn) in tetrahydrofuran (THF) at 200 K provides air-sensitive but thermally stable (at 293 K) solutions from which yellow crystalline blocks of bis[bis(tetrahydrofuran-κO)potassium] bis(μ-anthracene-κC:C)dicopper, [K(THF)][{Cu(9,10-η-CH)}] or [K(CHO)][Cu(CH)], 1, were isolated in about 50% yield. Single-crystal X-ray crystallographic analysis of 1 confirmed the presence of the first known (arene)cuprate. Also, unlike all previously known homoleptic (anthracene)metallates of d-block elements, which contain metals coordinated only to terminal rings, the organocuprate unit in 1 contains copper bound to the 9,10-carbons of the central ring of anthracene. No other d- or f-block metal is known to afford an anthracene or other aromatic hydrocarbon complex having the architecture of organodicuprate 1.
在200 K下，（三环己基膦）氯化亚铜与两当量的蒽钾（KAn）在四氢呋喃（THF）中反应，得到对空气敏感但热稳定（在293 K）的溶液，从中以约50%的产率分离出双[双（四氢呋喃-κO）钾]双（μ-蒽-κC:C）二铜，[K(THF)][{Cu(9,10-η-CH)}]或[K(CHO)][Cu(CH)]，即化合物1的黄色晶体块。对化合物1进行单晶X射线晶体学分析，证实了首个已知的（芳烃）铜酸盐的存在。此外，与所有先前已知的d族元素的均配（蒽）金属酸盐不同，后者所含金属仅与末端环配位，化合物1中的有机铜酸盐单元含有与蒽中心环的9,10-碳相连的铜。已知没有其他d族或f族金属能得到具有有机二铜酸盐1结构的蒽或其他芳烃配合物。
Zotero 插件