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电磁诱导吸收突破光吸收上限:等离子体-电介质二聚体中具有相位延迟的偶极-偶极耦合

Electromagnetically Induced Absorption Overcomes the Upper Limit of Light Absorption: Dipole-Dipole Coupling with Phase Retardation in Plasmonic-Dielectric Dimers.

作者信息

Matsumori Kishin, Fujimura Ryushi, Retsch Markus

机构信息

Department of Chemistry, Physical Chemistry I, University of Bayreuth, Bayreuth 95447, Germany.

Graduate School of Regional Development and Creativity, Utsunomiya University, Utsunomiya 321-8585, Japan.

出版信息

J Phys Chem C Nanomater Interfaces. 2023 Sep 15;127(38):19127-19140. doi: 10.1021/acs.jpcc.3c03307. eCollection 2023 Sep 28.

Abstract

Electromagnetically induced absorption (EIA) by a phase-retarded coupling is theoretically investigated using a dimer composed of a plasmonic and dielectric particle. This phase-retarded coupling originates from the particles interacting with each other through their scattered intermediate fields (in between near and far fields). Our analysis based on the coupled-dipole method and an extended coupled-oscillator model indicates that EIA by the phase-retarded coupling occurs due to constructive interference in the scattered fields of the particles. By employing the finite element method, we demonstrate that the absorption of the plasmonic particle is dramatically enhanced by tuning the interparticle distance and achieving constructive interference. In contrast to EIA by near-field coupling, which has been intensively researched using coupled plasmonic systems, EIA by a phase-retarded coupling enables us to strengthen the absorption of plasmonic systems more significantly. This significant absorption enhancement is expected to be beneficial to advancing various applications, such as energy harvesting and radiative cooling.

摘要

利用由等离子体粒子和介电粒子组成的二聚体,从理论上研究了相位延迟耦合引起的电磁诱导吸收(EIA)。这种相位延迟耦合源于粒子通过其散射的中间场(介于近场和远场之间)相互作用。我们基于耦合偶极子方法和扩展耦合振荡器模型的分析表明,相位延迟耦合引起的EIA是由于粒子散射场中的相长干涉而发生的。通过采用有限元方法,我们证明了通过调节粒子间距离并实现相长干涉,可以显著增强等离子体粒子的吸收。与使用耦合等离子体系统深入研究的近场耦合引起的EIA不同,相位延迟耦合引起的EIA使我们能够更显著地增强等离子体系统的吸收。这种显著的吸收增强有望有利于推进各种应用,如能量收集和辐射冷却。

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