Relieving Stress Concentration through Anion-Cation Codoping toward Highly Stable Nickel-Rich Cathode.

Nickel-rich LiNiCoAlO (NCA) with excellent energy density is considered one of the most promising cathodes for lithium-ion batteries. Nevertheless, the stress concentration caused by Li/Ni mixing and oxygen vacancies leads to the structural collapse and obvious capacity degradation of NCA. Herein, a facile codoping of anion (F)-cation (Mg) strategy is proposed to address these problems. Benefiting from the synergistic effect of F and Mg, the codoped material exhibits alleviated Li/Ni mixing and demonstrates enhanced electrochemical performance at high voltage (≥4.5 V), outperformed the pristine and F/Mg single-doped counterparts. Combined experimental and theoretical studies reveal that Mg and F codoping decreases the Li diffusion energy barrier and enhances the Li transport kinetics. In particular, the codoping synergistically suppresses the Li/Ni mixing and lattice oxygen escape, and alleviates the stress-strain accumulation, thereby inhibiting crack propagation and improving the electrochemical performance of the NCA. As a consequence, the designed LiMgNiCoAlOF (Mg1+F2) demonstrates a much higher capacity retention of 82.65% than NCA (55.69%) even after 200 cycles at 2.8-4.5 V under 1 C. Furthermore, the capacity retention rate of the Mg1+F2||graphite pouch cell after 500 cycles is 89.6% compared to that of the NCA (only 79.4%).