Ma Jun, Song Jinlong
State Key Laboratory of High-performance Precision Manufacturing, Dalian University of Technology, Dalian 116024, China; Key Laboratory for Micro/Nano Technology and System of Liaoning Province, Dalian University of Technology, Dalian, Liaoning 116024, China.
State Key Laboratory of High-performance Precision Manufacturing, Dalian University of Technology, Dalian 116024, China; Key Laboratory for Micro/Nano Technology and System of Liaoning Province, Dalian University of Technology, Dalian, Liaoning 116024, China.
J Colloid Interface Sci. 2024 Jan;653(Pt B):1548-1556. doi: 10.1016/j.jcis.2023.09.197. Epub 2023 Oct 2.
Slippery liquid-infused porous surface (SLIPS) has shown significant application values in various areas and has been commonly obtained by injecting the water-immiscible lubricant into a low-surface-energy modified micro/nano-structured surface. Constrained by the availability of desirable structured substrates or simple preparation schemes, the exploration of SLIPS with multifunctionality and universality that is facile to fabricate and robust in realistic applications remains challenging. Herein, we propose a one-step, fluoride-free and unconventional protocol based on a one-pot reaction of polysilazane (PSZ), silicone oils and multiwalled carbon nanotubes (MWCNT), which creates not only the favorable micro/nano-scale physical structures and surface chemistry for the excellent slippery property (sliding angle < 3°) and robust lubricant retention, but also the superior photothermal responsiveness for the potential multifunctional applications. It has been demonstrated that the proposed multifunctional slippery photothermal coating (MSPC) displayed outstanding potential in corrosion resistance, droplet manipulation and anti/de-icing. We envision that the proposed strategy could be realized in the real-life applications.
注入滑液的多孔表面(SLIPS)在各个领域都显示出显著的应用价值,通常是通过将与水不混溶的润滑剂注入低表面能改性的微/纳米结构表面来获得。受理想结构化基材的可用性或简单制备方案的限制,探索具有多功能性和通用性、易于制造且在实际应用中坚固耐用的SLIPS仍然具有挑战性。在此,我们提出了一种基于聚硅氮烷(PSZ)、硅油和多壁碳纳米管(MWCNT)的一锅法反应的一步、无氟且非常规的方案,该方案不仅为优异的滑爽性能(滑动角<3°)和强大的润滑剂保留创造了有利的微/纳米级物理结构和表面化学,还为潜在的多功能应用创造了卓越的光热响应性。已经证明,所提出的多功能滑爽光热涂层(MSPC)在耐腐蚀、液滴操控和防/除冰方面显示出突出的潜力。我们设想所提出的策略可以在实际应用中实现。