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全固态锂电池中金属有机框架复合固态聚合物电解质的当前研究综述

A mini review of current studies on metal-organic frameworks-incorporated composite solid polymer electrolytes in all-solid-state lithium batteries.

作者信息

Le Phuoc-Anh, Nguyen Nghia Trong, Nguyen Phi Long, Phung Thi Viet Bac, Do Cuong Danh

机构信息

Center for Environmental Intelligence and College of Engineering and Computer Science, VinUniversity, Hanoi, 100000, Viet Nam.

Institute of Sustainability Science, Vietnam Japan University, Vietnam National University, Hanoi, 100000, Viet Nam.

出版信息

Heliyon. 2023 Sep 7;9(9):e19746. doi: 10.1016/j.heliyon.2023.e19746. eCollection 2023 Sep.

Abstract

All-solid-state lithium batteries (ASSLBs) using solid polymer electrolytes (SPEs) are believed to be future next-generation batteries aiming to replace high-risk traditional batteries using liquid electrolytes, which have a wide application range in portable electronic devices, portable power supplies, and especially in electric vehicles. Moreover, the appearance of SPEs can overcome the electrolyte leakage and flammability problems in conventional lithium-ion batteries. Nevertheless, ASSLBs still face some limitations due to the low ionic conductivity of solid-state electrolytes (SSEs) at room temperature and the poor contact electrode/electrolyte interface, which can be solved by suitable strategies. Currently, the research strategies of metal-organic frameworks that can be incorporated into solid polymer electrolytes offer a remarkable method for producing uniform solid polymer electrolytes that have good electrode/electrolyte contact interfaces and high ionic conductivity. Herein, the updates of current studies about metal-organic framework-incorporated composite solid polymer electrolytes are discussed in this mini-review.

摘要

使用固体聚合物电解质(SPE)的全固态锂电池(ASSLB)被认为是未来旨在取代使用液体电解质的高风险传统电池的下一代电池,液体电解质在便携式电子设备、便携式电源,尤其是电动汽车中有着广泛的应用范围。此外,SPE的出现可以克服传统锂离子电池中的电解质泄漏和易燃性问题。然而,由于室温下固态电解质(SSE)的离子电导率低以及电极/电解质界面接触不良,ASSLB仍然面临一些限制,这些问题可以通过合适的策略来解决。目前,可掺入固体聚合物电解质的金属有机框架的研究策略为制备具有良好电极/电解质接触界面和高离子电导率的均匀固体聚合物电解质提供了一种显著的方法。在此,本综述讨论了当前关于掺入金属有机框架的复合固体聚合物电解质的研究进展。

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