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聚[[μ-1,3-双（吡啶-3-基）脲]双（μ-戊二酸根）二铜（II）]

Poly[[μ-1,3-bis-(pyridin-3-yl)urea]bis-(μ-glutarato)dicopper(II)].

作者信息

Ezenyilimba Frederick C, LaDuca Robert L

机构信息

E-35 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USA.

出版信息

IUCrdata. 2023 Sep 26;8(Pt 9):x230833. doi: 10.1107/S2414314623008337. eCollection 2023 Sep.

DOI:10.1107/S2414314623008337
PMID:37818463
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10561227/
Abstract

The title compound, [Cu(CHO)(CHNO)], contains square-pyramidally coordinated Cu ions linked by conformation glutarate (glu) ligands into [Cu(glu)] di-periodic coordination polymer layers with embedded [Cu(OCO)] paddlewheel clusters. In turn, the layer motifs are connected by 1,3-di(pyridin-3-yl)urea (3-dpu) linkers to form a [Cu(glu)(3-dpu)] tri-periodic coordination polymer network. Treating the [Cu(OCO)] clusters as 6-connected nodes reveals an underlying 46 topology according to software [Blatov (2014 ▸). , 3576-3586].

摘要

标题化合物[Cu(CHO)(CHNO)]包含呈四方锥配位的铜离子，这些铜离子通过构象戊二酸酯（戊二酸，glu）配体连接成具有嵌入[Cu(OCO)]桨轮簇的[Cu(glu)]二维周期配位聚合物层。反过来，这些层状结构单元通过1,3-二（吡啶-3-基）脲（3-dpu）连接体相连，形成一个[Cu(glu)(3-dpu)]三维周期配位聚合物网络。根据软件[Blatov (2014 ▸). , 3576 - 3586]，将[Cu(OCO)]簇视为6连接节点可揭示出一种潜在的46拓扑结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/f4392ef51387/x-08-x230833-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/8692d58fc304/x-08-x230833-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/208eaf490e72/x-08-x230833-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/b8e771a1f361/x-08-x230833-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/f4392ef51387/x-08-x230833-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/8692d58fc304/x-08-x230833-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/208eaf490e72/x-08-x230833-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/b8e771a1f361/x-08-x230833-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac82/10561227/f4392ef51387/x-08-x230833-fig4.jpg

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本文引用的文献

1
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J Appl Crystallogr. 2015 Jan 30;48(Pt 1):3-10. doi: 10.1107/S1600576714022985. eCollection 2015 Feb 1.