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用于生物医学应用的CoCrMoNbTi高熵合金的固态加工

Solid-State Processing of CoCrMoNbTi High-Entropy Alloy for Biomedical Applications.

作者信息

Bololoi Alina Elena, Geambazu Laura Elena, Antoniac Iulian Vasile, Bololoi Robert Viorel, Manea Ciprian Alexandru, Cojocaru Vasile Dănuţ, Pătroi Delia

机构信息

Materials Science and Engineering Faculty, National University of Science and Technology Politehnica Bucharest, Splaiul Independentei 313, 060042 Bucharest, Romania.

National Institute for R&D in Electrical Engineering ICPE-CA Bucharest, Splaiul Unirii 313, 030138 Bucharest, Romania.

出版信息

Materials (Basel). 2023 Sep 30;16(19):6520. doi: 10.3390/ma16196520.

Abstract

High-entropy alloys (HEAs) gained interest in the field of biomedical applications due to their unique effects and to the combination of the properties of the constituent elements. In addition to the required property of biocompatibility, other requirements include properties such as mechanical resistance, bioactivity, sterility, stability, cost effectiveness, etc. For this paper, a biocompatible high-entropy alloy, defined as bio-HEA by the literature, can be considered as an alternative to the market-available materials due to their superior properties. According to the calculation of the valence electron concentration, a majority of body-centered cubic (BCC) phases were expected, resulting in properties such as high strength and plasticity for the studied alloy, confirmed by the XRD analysis. The tetragonal (TVC) phase was also identified, indicating that the presence of face-centered cubic (FCC) phases in the alloyed materials resulted in high ductility. Microstructural and compositional analyses revealed refined and uniform metallic powder particles, with a homogeneous distribution of the elemental particles observed from the mapping analyses, indicating that alloying had occurred. The technological characterization of the high-entropy alloy-elaborated powder revealed the particle dimension reduction due to the welding and fracturing process that occurs during mechanical alloying, with a calculated average particle size of 45.12 µm.

摘要

高熵合金(HEAs)因其独特的效应以及组成元素性能的组合,在生物医学应用领域受到关注。除了所需的生物相容性特性外,其他要求还包括机械抗性、生物活性、无菌性、稳定性、成本效益等特性。就本文而言,一种生物相容性高熵合金,文献中定义为生物高熵合金(bio-HEA),由于其优越的性能,可以被视为市售材料的替代品。根据价电子浓度的计算,预计会出现大多数体心立方(BCC)相,这使得所研究的合金具有高强度和可塑性等性能,X射线衍射(XRD)分析证实了这一点。还鉴定出了四方相(TVC),表明合金材料中面心立方(FCC)相的存在导致了高延展性。微观结构和成分分析揭示了细化且均匀的金属粉末颗粒,从映射分析中观察到元素颗粒分布均匀,表明发生了合金化。对高熵合金制成的粉末进行的工艺表征显示,由于机械合金化过程中发生的焊接和破碎过程,颗粒尺寸减小,计算得出的平均粒径为45.12 µm。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/183e/10573847/3a7e93a1371f/materials-16-06520-g001.jpg

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