Gong Yafeng, Wu Shuzheng, Bi Haipeng, Tian Lihua
College of Transportation, Jilin University, Changchun 130025, China.
Polymers (Basel). 2023 Oct 1;15(19):3968. doi: 10.3390/polym15193968.
Carbon nanotubes (CNTs) and styrene-butadiene-styrene (SBS) are used as reinforcing modifiers in asphalt sealants due to their excellent properties, which can effectively improve the internal structure of the sealant and enhance its mechanical properties. Based on this background, two SBS/CNT-modified asphalt sealants were identified and selected by the orthogonal experimental method and compared with two commercially available sealants. The softening point, flow value, multi-temperature frequency scan test, and multiple stress creep recovery test were used to study the high-temperature rheological properties and aging resistance of four types of sealants. The overall evaluation shows that the proportion of the sealant compound's preparation material is 1% by weight of CNT doping, 5% by weight of SBS doping, and 5% by weight of furfural-extracted-oil doping. The results show that the addition of SBS and CNTs more significantly improves the fatigue resistance of the sealants. With the CAM model, C1.0S5F5 reflects a better relaxation property, which better avoids secondary cracking after the construction of the sealant. With the Burgers model, C1.0S5F5 shows excellent deformation resistance under heavy traffic conditions. In summary, conventional performance indicators, such as the softening point and flow value of SBS/CNT-modified asphalt sealants, can meet the specification requirements and show good high-temperature stability and anti-aging properties compared to commercially available sealants.
碳纳米管(CNTs)和苯乙烯-丁二烯-苯乙烯(SBS)由于其优异的性能,被用作沥青密封胶的增强改性剂,可有效改善密封胶的内部结构并提高其力学性能。基于此背景,通过正交试验方法确定并选择了两种SBS/CNT改性沥青密封胶,并与两种市售密封胶进行比较。采用软化点、流动值、多温频率扫描试验和多重应力蠕变恢复试验研究了四种密封胶的高温流变性能和耐老化性能。综合评价表明,密封胶复合材料制备材料的比例为:碳纳米管掺杂1%(重量)、SBS掺杂5%(重量)、糠醛抽出油掺杂5%(重量)。结果表明,添加SBS和碳纳米管能更显著地提高密封胶的抗疲劳性能。采用CAM模型时,C1.0S5F5表现出较好的松弛性能,能更好地避免密封胶施工后出现二次开裂。采用Burgers模型时,C1.0S5F5在重交通条件下表现出优异的抗变形能力。综上所述,SBS/CNT改性沥青密封胶的软化点和流动值等常规性能指标能够满足规范要求,与市售密封胶相比,具有良好的高温稳定性和抗老化性能。