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低温烟气中用于去除NO和CO的锰基催化剂综述:性能与机理

A Review of Mn-Based Catalysts for Abating NO and CO in Low-Temperature Flue Gas: Performance and Mechanisms.

作者信息

Li Xiaodi, Ren Shan, Chen Zhichao, Wang Mingming, Chen Lin, Chen Hongsheng, Yin Xitao

机构信息

College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China.

School of Physics and Optoelectronic Engineering, Ludong University, Yantai 264000, China.

出版信息

Molecules. 2023 Sep 30;28(19):6885. doi: 10.3390/molecules28196885.

DOI:10.3390/molecules28196885
PMID:37836730
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10574052/
Abstract

Mn-based catalysts have attracted significant attention in the field of catalytic research, particularly in NO catalytic reductions and CO catalytic oxidation, owing to their good catalytic activity at low temperatures. In this review, we summarize the recent progress of Mn-based catalysts for the removal of NO and CO. The effects of crystallinity, valence states, morphology, and active component dispersion on the catalytic performance of Mn-based catalysts are thoroughly reviewed. This review delves into the reaction mechanisms of Mn-based catalysts for NO reduction, CO oxidation, and the simultaneous removal of NO and CO. Finally, according to the catalytic performance of Mn-based catalysts and the challenges faced, a possible perspective and direction for Mn-based catalysts for abating NO and CO is proposed. And we expect that this review can serve as a reference for the catalytic treatment of NO and CO in future studies and applications.

摘要

锰基催化剂因其在低温下具有良好的催化活性,在催化研究领域引起了广泛关注,特别是在NO催化还原和CO催化氧化方面。在本综述中,我们总结了锰基催化剂在去除NO和CO方面的最新进展。深入探讨了结晶度、价态、形态和活性组分分散对锰基催化剂催化性能的影响。本综述还深入研究了锰基催化剂用于NO还原、CO氧化以及同时去除NO和CO的反应机理。最后,根据锰基催化剂的催化性能和面临的挑战,提出了锰基催化剂在减少NO和CO方面可能的前景和方向。我们期望本综述能够为未来研究和应用中NO和CO的催化处理提供参考。

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本文引用的文献

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Promotional effects of Nb and Fe co-doping on catalytic performance and SO resistance of MnO-CeO low-temperature denitration catalyst.Nb 和 Fe 共掺杂对 MnO-CeO 低温脱硝催化剂的催化性能和 SO 抗性的促进作用。
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Coadsorption Interfered CO Oxidation over Atomically Dispersed Au on -BN.原子分散的 Au 负载在 -BN 上对共吸附 CO 氧化的干扰。
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Promotional effects of nitrogen doping on catalytic performance over manganese-containing semi-coke catalysts for the NH-SCR at low temperatures.氮掺杂对含锰半焦催化剂低温NH-SCR催化性能的促进作用。
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Single Pt atom supported on penta-graphene as an efficient catalyst for CO oxidation.负载在五石墨烯上的单铂原子作为一氧化碳氧化的高效催化剂。
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