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微波合成的氮掺杂碳点用于汞(II)离子的双模式检测及孔雀石绿染料的降解

Microwave synthesized N-doped carbon dots for dual mode detection of Hg(II) ion and degradation of malachite green dye.

作者信息

Thara Chinnu R, Mathew Beena

机构信息

School of Chemical Sciences, Mahatma Gandhi University, Kottayam, 686560, Kerala, India.

School of Chemical Sciences, Mahatma Gandhi University, Kottayam, 686560, Kerala, India.

出版信息

Talanta. 2024 Feb 1;268(Pt 1):125278. doi: 10.1016/j.talanta.2023.125278. Epub 2023 Oct 5.

Abstract

One of the most intriguing materials today is carbon dots, which offer a variety of possible uses owing to their distinct photophysical and chemical characteristics. The current study examines the electrochemical and photochemical aspects of carbon dots produced in a single pot for environmental sustainability. Domestic microwave-assisted pyrolysis of urea and glucose yielded chemically synthesized nitrogen-doped carbon dots (microwave synthesized N-doped carbon dots (M-NCDs)) with blue fluorescence and a quantum yield of 14.9 %. High water dispersibility, stability, and biocompatibility were the significant attributes of synthesized M-NCDs. Customarily fluorescent carbon dots were initially used for sensing studies. Fluorescent and electrochemical studies manifest the excellent stability, sensitivity, and selectivity of M-NCDs for mercuric ions. Both methods' Hg (II) procure detection limits of 3.5 nM and 6.1 nM. In addition to sensing traits, the subsequent section deals with the potential of M-NDCs to bring about the exhaustive degradation of malachite green (MG) dye. Within 60 min, 98 % of the dye was catalytically degraded by M-NCD by first-order kinetics based on the Langmuir-Hinshelwood model. This is the first time reporting the catalytic degradation of malachite green dye utilizing carbon dot in its natural form rather than being doped with any metal atom or converted to any composite form.

摘要

如今最具吸引力的材料之一是碳点,由于其独特的光物理和化学特性,它有多种可能的用途。当前的研究考察了在单锅中制备的碳点的电化学和光化学特性,以实现环境可持续性。通过家用微波炉辅助尿素和葡萄糖的热解,得到了化学合成的具有蓝色荧光且量子产率为14.9%的氮掺杂碳点(微波合成氮掺杂碳点(M-NCDs))。高水分散性、稳定性和生物相容性是合成的M-NCDs的显著特性。传统上,荧光碳点最初用于传感研究。荧光和电化学研究表明,M-NCDs对汞离子具有出色的稳定性、灵敏度和选择性。两种方法对Hg(II)的检测限分别为3.5 nM和6.1 nM。除了传感特性外,后续部分还探讨了M-NDCs对孔雀石绿(MG)染料进行彻底降解的潜力。在60分钟内,基于朗缪尔-欣谢尔伍德模型,M-NCD通过一级动力学催化降解了98%的染料。这是首次报道利用天然形式的碳点而非掺杂任何金属原子或转化为任何复合形式来催化降解孔雀石绿染料。

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