通过镍-铝双金属催化的C-P键活化实现炔烃与氧化膦的分子间碳膦化反应
Intermolecular Carbophosphination of Alkynes with Phosphole Oxides via Ni-Al Bimetal-Catalyzed C-P Bond Activation.
作者信息
Zhang Feng-Ping, Wang Rong-Hua, Li Jiang-Fei, Chen Hao, Hari Babu Madala, Ye Mengchun
机构信息
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Haihe Laboratory of Sustainable Chemical Transformations, Frontiers Science Center for New Organic Matter, Nankai University, Tianjin, 300071, China.
出版信息
Angew Chem Int Ed Engl. 2023 Dec 4;62(49):e202314701. doi: 10.1002/anie.202314701. Epub 2023 Oct 31.
Intermolecular carbophosphination reaction of alkynes or alkenes with unreactive C-P bonds remains an elusive challenge. Herein, we used a Ni-Al bimetallic catalyst to realize an intermolecular carbophosphination reaction of alkynes with 5-membered phosphole oxides, providing a series of 7-membered phosphepines in up to 94 % yield.
炔烃或烯烃与惰性碳-磷键的分子间碳磷酰化反应仍然是一个难以实现的挑战。在此，我们使用镍-铝双金属催化剂实现了炔烃与五元磷杂环氧化合物的分子间碳磷酰化反应，以高达94%的产率提供了一系列七元磷杂环庚三烯。
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