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用于反照率环境的双面半透明钙钛矿/铜铟硒叠层太阳能电池中双面半透明铜铟硒吸收体在底部电池的应用。

Application of Bifacial Semitransparent CuInSe Absorber to the Bottom Cell in Bifacial Semitransparent Perovskite/CuInSe Tandem Solar Cell for Albedo Environment.

作者信息

An Jin Gi, Tran Huyen, Kim Dongryeol, Lee Sang Min, Lee Ahreum, Ahn Seung Kyu, Cho Jun-Sik, Gwak Jihye, Kim TaeWan, Jeong Inyoung, Park Joo Hyung

机构信息

Photovoltaics Research Department, Korea Institute of Energy Research (KIER), Daejeon, 34129, Republic of Korea.

Department of Electrical Engineering and Smart Grid Research Center, Jeonbuk National University, Jeonju, 54896, Republic of Korea.

出版信息

Small. 2024 Mar;20(9):e2305796. doi: 10.1002/smll.202305796. Epub 2023 Oct 19.

Abstract

Although various types of bifacial solar cells exist, few studies have been conducted on bifacial semitransparent CuInSe solar cells (BS-CISe SCs) despite the attractive potential in power generation from both sides in an albedo environment. The optimized BS-CISe SCs with 300 and 800 nm-thick absorber via a streamlined single-stage co-evaporation process exhibit a power conversion efficiency (PCE) of 6.32% and 10.6%, respectively. When double-sided total 2.0 sun illumination is assumed in an albedo environment, the bifacial power generation densities (BPGD) of them increases to 9.41% and 13.9%. Four-terminal bifacial semitransparent tandem solar cells (4T-BST SCs) are fabricated to increase the BPGD by mechanically stacking a BS-perovskite (PVK) top cell on top of a BS-CISe bottom cell with the 300 and 800 nm-thick absorber layers. When summed up, the best top and bottom cell PCEs of the 4T-BST SC with 300 and 800 nm-thick BS-CISe SC are 18.8% and 21.1%, respectively. However, the practical BPGD values of the 4T-BST SC under total 2 sun illumination are interestingly 23.4% and 24.4%, respectively. This is because the BS-CISe bottom cell's thickness affects how much rear-side illumination is transmitted to the BS-PVK top cell, increasing its current density and BPGD.

摘要

尽管存在各种类型的双面太阳能电池,但对于双面半透明铜铟硒太阳能电池(BS-CISe SCs)的研究却很少,尽管其在反照率环境中双面发电具有诱人的潜力。通过简化的单阶段共蒸发工艺制备的具有300和800纳米厚吸收层的优化BS-CISe SCs的功率转换效率(PCE)分别为6.32%和10.6%。在反照率环境中假设双面总光照为2.0太阳时,它们的双面发电密度(BPGD)分别增加到9.41%和13.9%。通过将具有300和800纳米厚吸收层的BS-钙钛矿(PVK)顶部电池机械堆叠在BS-CISe底部电池之上,制备了四端双面半透明串联太阳能电池(4T-BST SCs),以提高BPGD。综上所述,具有300和800纳米厚BS-CISe SC的4T-BST SC的最佳顶部和底部电池PCE分别为18.8%和21.1%。然而,有趣的是,在总光照为2太阳的情况下,4T-BST SC的实际BPGD值分别为23.4%和24.4%。这是因为BS-CISe底部电池的厚度会影响背面光照传输到BS-PVK顶部电池的量,从而增加其电流密度和BPGD。

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