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商用室内光活性涂料上的光化学再氧化作用

Photochemical renoxification on commercial indoor photoactive paint.

作者信息

Vallieres Morgan, Jones Stephanie H, Schwartz-Narbonne Heather, Donaldson D James

机构信息

Department of Chemistry, University of Toronto, Toronto, Canada.

Department of Physical and Environmental Sciences, University of Toronto Scarborough, Toronto, Canada.

出版信息

Sci Rep. 2023 Oct 19;13(1):17835. doi: 10.1038/s41598-023-44927-5.

DOI:10.1038/s41598-023-44927-5
PMID:37857714
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10587164/
Abstract

Surface chemistry plays an important role in the indoor environment owing to the large indoor surface to volume ratio. This study explores the photoreactivity of surfaces painted with a photoactive paint in the presence of NO. Two types of experiments are performed; illumination of painted surfaces with a nitrate deposit and illumination of painted surfaces in the presence of gaseous NO. For both types of experiments, illumination with a fluorescent bulb causes the greatest change in measured gaseous NO concentrations. Results show that relative humidity and paint composition play an important role in the photoreactivity of indoor painted surfaces. Painted surfaces could contribute to gas-phase oxidant concentrations indoors.

摘要

由于室内表面积与体积之比很大,表面化学在室内环境中起着重要作用。本研究探讨了在有一氧化氮(NO)存在的情况下,涂有光活性涂料的表面的光反应性。进行了两种类型的实验:用硝酸盐沉积物照射涂漆表面以及在气态NO存在下照射涂漆表面。对于这两种类型的实验,用荧光灯泡照射会导致测得的气态NO浓度发生最大变化。结果表明,相对湿度和涂料成分在室内涂漆表面的光反应性中起着重要作用。涂漆表面可能会导致室内气相氧化剂浓度升高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/0c0f98628070/41598_2023_44927_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/13e054dc3028/41598_2023_44927_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/d4b9ae38edef/41598_2023_44927_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/0d4c00bb10e9/41598_2023_44927_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/8f0c1644845f/41598_2023_44927_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/0c0f98628070/41598_2023_44927_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/13e054dc3028/41598_2023_44927_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/d4b9ae38edef/41598_2023_44927_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/0d4c00bb10e9/41598_2023_44927_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/8f0c1644845f/41598_2023_44927_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cad/10587164/0c0f98628070/41598_2023_44927_Fig5_HTML.jpg

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1
Photochemical renoxification on commercial indoor photoactive paint.商用室内光活性涂料上的光化学再氧化作用
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本文引用的文献

1
Comprehensive Study about the Photolysis of Nitrates on Mineral Oxides.矿物氧化物中硝酸盐的光解综合研究。
Environ Sci Technol. 2021 Jul 6;55(13):8604-8612. doi: 10.1021/acs.est.1c02182. Epub 2021 Jun 16.
2
Loss of NO(g) to painted surfaces and its re-emission with indoor illumination.NO(g) 向涂漆表面的损失及其在室内光照下的再发射。
Indoor Air. 2021 Mar;31(2):566-573. doi: 10.1111/ina.12741. Epub 2020 Sep 25.
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Water uptake by indoor surface films.室内表面薄膜的吸水性。
Sci Rep. 2019 Jul 31;9(1):11089. doi: 10.1038/s41598-019-47590-x.
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Human exposure to NO in school and office indoor environments.人体在学校和办公室内环境中接触 NO。
Environ Int. 2019 Sep;130:104887. doi: 10.1016/j.envint.2019.05.081. Epub 2019 Jun 10.
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Illuminating the dark side of indoor oxidants.揭示室内氧化剂的阴暗面。
Environ Sci Process Impacts. 2019 Aug 14;21(8):1229-1239. doi: 10.1039/c9em00111e.
6
Production of HO and OH radicals from near-UV irradiated airborne TiO nanoparticles.空气中 TiO 纳米粒子经近紫外辐射产生 HO 和 OH 自由基。
Phys Chem Chem Phys. 2019 Jan 30;21(5):2325-2336. doi: 10.1039/c8cp06889e.
7
Optimization of the NO photooxidation and the role of relative humidity.优化 NO 光氧化作用及相对湿度的作用。
Environ Pollut. 2018 Sep;240:541-548. doi: 10.1016/j.envpol.2018.04.051. Epub 2018 May 11.
8
An indoor chemical cocktail.室内化学混合物。
Science. 2018 Feb 9;359(6376):632-633. doi: 10.1126/science.aar6837.
9
Indoor Chemistry.室内化学。
Environ Sci Technol. 2018 Mar 6;52(5):2419-2428. doi: 10.1021/acs.est.7b06387. Epub 2018 Feb 15.
10
Wavelength-Resolved Photon Fluxes of Indoor Light Sources: Implications for HO Production.室内光源的波长分辨光子通量:对 HO 生成的影响。
Environ Sci Technol. 2017 Sep 19;51(18):10423-10430. doi: 10.1021/acs.est.7b02015. Epub 2017 Aug 29.