Fabrication of all-chitin composite films.

The aim of this study is to propose a first concept for the procedure to prepare an all-chitin composite. The fabrication of all-chitin composite films was investigated for the first time via the mixing of low-crystalline matrix dispersions with high-crystalline fiber dispersions. Self-assembled chitin nanofiber (ChNF) films, prepared from a chitin ion gel, were treated with aqueous NaOH for deacetylation, followed by treatment with different types of aqueous acids via ultrasonication to produce dispersions. When the treatment was carried out with 1.0 mol/L aqueous acetic acid, we obtained a scaled-down ChNF (high-crystalline chitin fiber) dispersion, as previously reported. The crystallinity was reduced by treatment with 1.0 mol/L aqueous trifluoroacetic acid for 10 min at room temperature via ultrasonication and subsequent treatment for 24 h at 50 °C with stirring to produce a low-crystalline chitin matrix dispersion. The resulting two dispersions were mixed, and treated by suction filtration and drying to produce all-chitin composite films. The mechanical properties of the obtained composite films with appropriate weight ratios of the two components were superior to those of the high-crystalline scaled-down ChNF film. All-chitin complexes are expected to be used in the future as sustainable materials for a variety of applications.