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研究明胶增强玉米淀粉凝胶 3D 打印精度的机制:从相形态变化的角度。

Investigation of the mechanism of gelatin to enhance 3D printing accuracy of corn starch gel: From perspective of phase morphological changes.

机构信息

State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China; School of Food Science and Engineering, Qilu University of Technology, Shandong Academy of Sciences, Jinan, Shandong 250353, China; Department of Food Science and Engineering, Shandong Agricultural University, Taian 271018, China.

State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China; School of Food Science and Engineering, Qilu University of Technology, Shandong Academy of Sciences, Jinan, Shandong 250353, China.

出版信息

Int J Biol Macromol. 2024 Jan;254(Pt 2):127323. doi: 10.1016/j.ijbiomac.2023.127323. Epub 2023 Oct 23.

Abstract

The study examined the impact of phase morphological transformations within the corn starch/gelatin system, induced by varying gelatin content, on its rheological properties and 3D printing performance. Gelatin addition inhibited the gelatinization and retrogradation of starch, which leaded to the transformation of continuous phase structure. The transition process from starch continuous phase to gelatin continuous phase promoted a thinner wall structure of the gel and loosed its dense network, resulting in reduced flow stress (τ) and storage modulus (G'). These changes improved the extrusion and "extrusion swelling" of gel ink materials, which made the print size of printed product closer to the set model. The formation of a gelatin continuous phase in the gel was helpful in increasing τ and G', resulting in enhanced support capacity of the printed product. This study presented meaningful information for the application of 3D printing to starch-gelatin complex foods.

摘要

该研究考察了玉米淀粉/明胶体系中通过改变明胶含量引起的相形态转变对其流变性能和 3D 打印性能的影响。明胶的添加抑制了淀粉的糊化和回生,导致连续相结构的转变。从淀粉连续相向明胶连续相的转变过程促进了凝胶更薄的壁结构,并使其密集的网络变松,从而降低了流动应力(τ)和储能模量(G')。这些变化改善了凝胶油墨材料的挤出和“挤出膨胀”性能,使得打印产品的打印尺寸更接近设定的模型。凝胶中明胶连续相的形成有助于增加 τ 和 G',从而提高打印产品的支撑能力。本研究为 3D 打印在淀粉-明胶复合食品中的应用提供了有意义的信息。

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