Kelly-Walley Jake, Ortega Zaida, McCourt Mark, Millar Bronagh, Suárez Luis, Martin Peter
Matrix Polymers, Unit 2, Compass Industrial Park, Spindus Road, Speke, Liverpool L24 1YA, UK.
Polymer Processing Research Centre, School of Mechanical and Aerospace Engineering, Queen's University Belfast, Ashby Building, Stranmillis Road, Belfast BT9 5AH, Northern Ireland, UK.
Materials (Basel). 2023 Oct 18;16(20):6749. doi: 10.3390/ma16206749.
The incorporation of materials different from the polymer within the rotational molding process usually results in lowered mechanical properties, where impact strength is of particular concern. In order to overcome this issue, multilayer structures of virgin polyethylene (PE) and banana fiber composites were prepared to determine the impact of the different layers on the performance of the final part. Cycle time has been studied to identify the influence of the addition of fibers in the process. The tensile, flexural and impact properties have been analyzed, finding improvements in Young's modulus of up to 13%, although at the expense of significant decreases in impact strength. A reduction in the fiber size due to the pulverization process was observed, which affected the rheological and mechanical behavior of the composite. The beneficial effects of working in multiple layers have been demonstrated in this work, where composites with up to 5% of banana fiber have been produced in two-layer structures. Finally, the need to add neat polyethylene in the external layer is also highlighted as a way to counteract the reductions in mechanical properties, particularly for flexural elastic modulus and tensile strength, and this also helps with the drop in impact behavior to a lower extent.
在滚塑成型过程中加入不同于聚合物的材料通常会导致机械性能下降,其中冲击强度尤其值得关注。为了克服这个问题,制备了纯聚乙烯(PE)和香蕉纤维复合材料的多层结构,以确定不同层对最终部件性能的影响。研究了循环时间,以确定在该过程中添加纤维的影响。对拉伸、弯曲和冲击性能进行了分析,发现杨氏模量提高了13%,不过是以冲击强度显著降低为代价。观察到由于粉碎过程导致纤维尺寸减小,这影响了复合材料的流变学和力学行为。这项工作证明了多层加工的有益效果,其中在两层结构中制备了含高达5%香蕉纤维的复合材料。最后,还强调了在外层添加纯聚乙烯的必要性,以此来抵消机械性能的下降,特别是对于弯曲弹性模量和拉伸强度,并且这在一定程度上也有助于缓解冲击性能的下降。