Thomas Sabu, Ter-Zakaryan Karapet Armenovich, Zhukov Aleksey Dmitrievich, Bessonov Igor' Vyacheslavovich
School of Energy Materials, Mahatma Gandhi University, Kottayam 686560, Kerala, India.
OOO TEPOFOL, Moscow 105318, Russia.
Polymers (Basel). 2023 Oct 16;15(20):4104. doi: 10.3390/polym15204104.
Effective insulation of buildings and other industrial objects requires the use of materials and system solutions that ensure maximum uniformity and density of insulation shells. The study focuses on the development of insulation systems based on expanded polyethylene and, in particular, on the development of modified polyethylene with reduced flammability containing a flame-retardant modified montmorillonite clay, which does not hinder gas formation, and silicate nanofillers in layered construction. Active experiments based on mathematical design methods allowed us to establish an analytical relationship between flame-retardant and modifier consumption and extruder pressure and response functions: average density of polyethylene foam and flammability criterion. The flammability criterion was taken as the oxygen index of the modified polyethylene foam. A foaming agent masterbatch was used as the flame retardant. Analytical optimization of mathematical models obtained as a result of active experiments allowed us to determine the optimal flame-retardant consumption, which was 3.7-3.8% of the polymer mass. Optimised systems for average density and oxygen index of flammability of modified polyethylene were obtained. A nomogram for predicting the material properties and selecting the composition, and an algorithm for a computer program for evaluating the properties of modified polyethylene foam as a function of the values of various factors, were developed. Taking into account the possible expansion of the scope of application of rolled polyethylene foam and seamless insulation shells based on it, possible solutions for insulation systems were studied using the program THERM, and a combined insulation system was adopted.
建筑物和其他工业物体的有效隔热需要使用能够确保隔热层最大均匀性和密度的材料及系统解决方案。该研究聚焦于基于发泡聚乙烯的隔热系统的开发,尤其关注含有阻燃改性蒙脱石粘土(不阻碍气体生成)和层状结构硅酸盐纳米填料的低易燃性改性聚乙烯的开发。基于数学设计方法的积极实验使我们能够建立阻燃剂和改性剂用量与挤出机压力以及响应函数之间的分析关系:聚乙烯泡沫的平均密度和可燃性标准。可燃性标准采用改性聚乙烯泡沫的氧指数。使用发泡剂母料作为阻燃剂。对积极实验所得数学模型进行分析优化,使我们能够确定最佳阻燃剂用量,即聚合物质量的3.7 - 3.8%。获得了改性聚乙烯平均密度和可燃性氧指数的优化系统。开发了用于预测材料性能和选择组成的列线图,以及用于评估改性聚乙烯泡沫性能作为各种因素值函数的计算机程序算法。考虑到基于轧制聚乙烯泡沫及其无缝隔热层应用范围可能的扩大,使用THERM程序研究了隔热系统的可能解决方案,并采用了组合隔热系统。