A facile strategy for the preparation of carbon nanotubes/polybutadiene crosslinked composite membrane and its application in osmotic energy harvesting.

The osmotic energy between riverine water and seawater can be converted into electricity by reverse electrodialysis (RED). However, the facile fabrication of advanced RED membranes with high energy conversion efficiencies, large areas, and excellent mechanical properties remains a challenge. Carbon nanotubes (CNTs) exhibit excellent conductivity and provide suitable channels for ion transport but cannot form membranes independently, which limits the related applications in osmotic energy conversion. Herein, a new organic-inorganic composite membrane is prepared by combining hydroxyl-terminated polybutadiene as a matrix and carbon nanotubes as transport nanochannels. The nanotubes are pre-subjected to plasma treatment to increase the surface charge density and transport capacity of the nanochannels, improving the ion selectivity and energy conversion efficiency. Under actual seawater/river water conditions, the developed membrane delivers a power density of ∼5.1 W/m and shows good mechanical strength (219 MPa). Our work provides a facile solution to the problem posed by the inability of ideal nanochannels to form membranes independently and paves the way for the application of RED membranes in osmotic energy conversion.