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用于高效电磁波吸收和热管理的超柔性银/铁纳米线修饰三聚氰胺复合泡沫材料

Ultra-flexible silver/iron nanowire decorated melamine composite foams for high-efficiency electromagnetic wave absorption and thermal management.

作者信息

Hang Tianyi, Xu Chenhui, Shen Jiahui, Zheng Jiajia, Zhou Lijie, Li Mengjia, Li Xiping, Jiang Shaohua, Yang Pingan, Zhou Wei, Chen Yiming

机构信息

Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, College of Engineering, Zhejiang Normal University, Jinhua 321004, China.

Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology & Equipment of Zhejiang Province, College of Engineering, Zhejiang Normal University, Jinhua 321004, China.

出版信息

J Colloid Interface Sci. 2024 Jan 15;654(Pt B):945-954. doi: 10.1016/j.jcis.2023.10.117. Epub 2023 Oct 24.

Abstract

Nowadays, functional electronic devices with excellent flexibility and thermal management capability for effective electromagnetic wave absorption are urgently in demand. Herein, a novel and highly flexible silver nanowire (AgNW)/iron nanowire (FeNW) decorated melamine composite foam (AgFe-MF) was prepared via simple dip-coating process. Owing to optimal impedance matching, synergistic dielectric and magnetic losses as well as three-dimensional porous structure, the AgFe-MF with an ultra-low filler content (0.22 vol%) exhibited an outstanding minimum reflection loss of -69.61 dB, and the best effective absorption bandwidth (EAB) could reach up to 6.37 GHz. Importantly, the EAB of long-time working AgFe-MF was enhanced to 7.01 GHz after 1000 compress-release cycles under 40 % strain. Besides, it also featured considerate Joule heating capacity and achieved a saturation temperature of over 85.7 ℃ under 2.6 V voltage. The impressive thermal isolation and long-term stability ensured the safety used as portable heater. Therefore, this work will provide a vital slight for fabricating smart wearable electronic devices with integrated anti-electromagnetic radiation and personalized thermal management performances towards potential thermal and health threats.

摘要

如今,迫切需要具有出色柔韧性和热管理能力以实现有效电磁波吸收的功能性电子设备。在此,通过简单的浸涂工艺制备了一种新型的、高度柔性的银纳米线(AgNW)/铁纳米线(FeNW)装饰的三聚氰胺复合泡沫(AgFe-MF)。由于最佳的阻抗匹配、协同的介电和磁损耗以及三维多孔结构,具有超低填料含量(0.22体积%)的AgFe-MF表现出出色的最小反射损耗-69.61 dB,并且最佳有效吸收带宽(EAB)可达6.37 GHz。重要的是,在40%应变下经过1000次压缩-释放循环后,长期工作的AgFe-MF的EAB提高到了7.01 GHz。此外,它还具有可观的焦耳热能力,在2.6 V电压下实现了超过85.7℃的饱和温度。令人印象深刻的热隔离和长期稳定性确保了其作为便携式加热器使用的安全性。因此,这项工作将为制造具有集成抗电磁辐射和针对潜在热和健康威胁的个性化热管理性能的智能可穿戴电子设备提供至关重要的思路。

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