School of Engineering, RMIT University, Melbourne, VIC 3001, Australia.
School of Engineering, RMIT University, Melbourne, VIC 3001, Australia.
Sci Total Environ. 2024 Jan 10;907:168032. doi: 10.1016/j.scitotenv.2023.168032. Epub 2023 Oct 26.
Fats, oils, and grease (FOG) in wastewater generated by commercial food establishments can cause severe environmental damage if not adequately treated. Grease interceptors (GIs) are an effective solution to limit FOG disposal into the sewer, but their efficiency greatly depends on the wastewater's characteristics. This laboratory study examined the physical and chemical properties of synthetic FOG wastewater from handwashing sinks and dishwashers using cooked animal fats and oils, some food solids and the same amount of detergent to explore the impact of dishwashers on key FOG components that contribute to FOG depositions. Results showed that dishwasher-generated wastewater had a significant influence on fatty acid (FA) transformations, particularly in producing very long chain saturated FAs. Relative proportions of FAs revealed a considerable proportion of very long chain FAs, such as palmitoleic (C16:1), linoleic (C18:2), α-linolenic (C18:3), arachidic (C20:0), paullinic (C20:1), behenic (C22:0), erucic (C22:1), lignoceric (C24:0) and nervonic (C24:1), among which most were not highlighted in the real field FOG wastewater. These FAs may play a significant role in FOG solidification if not sufficiently removed before disposal to sewer. The study also found that dishwashers were able to break down FOG particles, creating smaller particles (75 % being ≤68.8 μm and 50 % being ≤7 μm), while handwashing sinks produced larger particles (50 % being ≤118 μm and 10 % being ≤7 μm and). Samples containing cooked animal fats were more likely to be fragmented into smaller sizes than cooking oils due to the impact of the dishwasher. Confocal microscopy analysis results were consistent with the particle sizes measured by laser diffraction. These distinct properties could serve as criteria for updating GI designs, limiting the amount of FOG and FAs disposed of in the sewer system and controlling solidification and blockages, which pose significant threats to the environment.
废水中的脂肪、油和油脂(FOG)如果未经适当处理,会对环境造成严重破坏。油脂截留器(GI)是限制 FOG 排入下水道的有效解决方案,但它们的效率在很大程度上取决于废水的特性。本实验室研究使用煮过的动物脂肪和油、一些食物固体和相同量的清洁剂,从手工清洗水槽和洗碗机中合成了 FOG 废水,以研究洗碗机对导致 FOG 沉积的关键 FOG 成分的影响。结果表明,洗碗机产生的废水对脂肪酸(FA)的转化有显著影响,特别是在产生非常长链饱和 FA 方面。FA 的相对比例显示出非常长链 FA 的相当大比例,如棕榈油酸(C16:1)、亚油酸(C18:2)、α-亚麻酸(C18:3)、花生酸(C20:0)、帕拉金酸(C20:1)、山嵛酸(C22:0)、芥酸(C22:1)、木蜡酸(C24:0)和神经酸(C24:1),其中大多数在实际 FOG 废水中并未突出显示。如果在排入下水道之前没有充分去除这些 FA,它们可能在 FOG 固化中发挥重要作用。该研究还发现,洗碗机能够分解 FOG 颗粒,形成更小的颗粒(75%的颗粒≤68.8μm,50%的颗粒≤7μm),而手洗水槽产生的颗粒更大(50%的颗粒≤118μm,10%的颗粒≤7μm和)。由于洗碗机的影响,含有煮过的动物脂肪的样品更容易碎裂成较小的尺寸,而不是烹饪油。共焦显微镜分析结果与激光衍射测量的颗粒尺寸一致。这些不同的特性可以作为更新 GI 设计的标准,限制排入下水道系统的 FOG 和 FA 的数量,并控制固化和堵塞,这对环境构成重大威胁。