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硫酸钠作用下镍铁渣水泥基复合材料力学性能及机理研究

Study on the Mechanical Properties and Mechanism of a Nickel-Iron Slag Cement-Based Composite under the Action of Sodium Sulfate.

作者信息

Zhang Jingyu, Zhou Yuwan, Chen Sili, Meng Jinzhu, Wang Junxiang

机构信息

School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China.

School of Architecture and Civil Engineering, Shenyang University of Technology, Shenyang 110870, China.

出版信息

Materials (Basel). 2023 Nov 4;16(21):7041. doi: 10.3390/ma16217041.

Abstract

The accumulated amount of nickel-iron slag has increased with the rapid development of the nickel-iron industry. To determine a method for comprehensively utilizing nickel-iron slag, triaxial compression tests of nickel-iron slag cement-based composite materials under the action of sodium sulfate were conducted, and the effects of the sodium sulfate concentration on the stress-strain relation, shear strength, cohesion, and internal friction angle of the composite materials were analyzed. In addition, the influence mechanism of the nickel-iron slag content and sodium sulfate concentration on the composite was examined. The results revealed that the stress-strain curve of the nickel-iron slag cement-based composites reflected softening. With the increase in the sodium sulfate concentration, the brittleness increased, while the shear strength, cohesion, and internal friction angle decreased; the addition of nickel-iron slag slowed down the rate at which these parameters decrease. Scanning electron microscopy images revealed that nickel-iron slag can improve the internal structure of the cement composite soil, enhance its compactness, and improve its corrosion resistance. The optimum nickel-iron slag content of 14% can improve the cementitious composites' resistance to sodium sulfate erosion in terms of solid waste utilization and cementitious soil performance. The results obtained can provide technical parameters for preparing and designing cement-based composite materials as well as certain theoretical significance and engineering reference value.

摘要

随着镍铁行业的快速发展,镍铁渣的堆积量不断增加。为确定镍铁渣的综合利用方法,进行了硫酸钠作用下镍铁渣水泥基复合材料的三轴压缩试验,分析了硫酸钠浓度对复合材料应力 - 应变关系、抗剪强度、黏聚力和内摩擦角的影响。此外,研究了镍铁渣含量和硫酸钠浓度对复合材料的影响机理。结果表明,镍铁渣水泥基复合材料的应力 - 应变曲线呈现软化现象。随着硫酸钠浓度的增加,脆性增大,抗剪强度、黏聚力和内摩擦角减小;镍铁渣的加入减缓了这些参数的降低速率。扫描电子显微镜图像显示,镍铁渣可改善水泥复合土的内部结构,增强其密实性,提高其抗侵蚀性。14%的最佳镍铁渣含量在固体废弃物利用和水泥土性能方面可提高水泥基复合材料的抗硫酸钠侵蚀能力。所得结果可为水泥基复合材料的制备与设计提供技术参数,具有一定的理论意义和工程参考价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e779/10647476/f25aed971eb1/materials-16-07041-g001.jpg

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